Enforced 2D supramolecular structures within hydrogen-bonded molecular cocrystals

Shengli Huang; Hongwei Hou; Liwei Mi; Yaoting Fan

doi:10.1080/00958970902741269

Enforced 2D supramolecular structures within hydrogen-bonded molecular cocrystals

Shengli Huang, Hongwei Hou^*, Liwei Mi, Yaoting Fan

^*Corresponding author for this work

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Two new coordination polymers,{[Co(btmb)₂(H₂O)₂](Fc(SO₃)₂)}_n(1) and{[Cd(bbbm) (H₂O)₄] · (p-FcC₆H₄SO₃)₂(CH₃OH)}_n(2)(Fc = ferrocene; btmb = 1,4-bis(triazol-1-ylmethyl)- benzene); bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole), were synthesized as cocrystals and characterized by single crystal X-ray diffraction, elemental analysis and IR spectrum. In 1, two btmb molecules link Co(II) ions into one 1D double-stranded chain of loops, and these chains are bridged by Fc(SO₃)₂^2- ligands through H-bonds, resulting in an infinite 2D sandwich-type network. In 2, two adjacent Cd(II) ions are interconnected by bbbm to generate a 1D zigzag chain structure, and p FcC₆H₄SO₃^- squeezes like a wedge into the adjacent chains, further being assembled by O-H . . . O hydrogen bonds and - stacking interactions to form a 2D supramolecular network.

Original language	English
Pages (from-to)	1964-1971
Number of pages	8
Journal	Journal of Coordination Chemistry
Volume	62
Issue number	12
DOIs	https://doi.org/10.1080/00958970902741269
Publication status	Published - Jun 2009
Externally published	Yes

Keywords

Cocrystal
Coordination polymer
Electrochemistry
H-bond
Sulfonates

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10.1080/00958970902741269

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title = "Enforced 2D supramolecular structures within hydrogen-bonded molecular cocrystals",

abstract = "Two new coordination polymers,{[Co(btmb)2(H2O)2](Fc(SO3)2)}n(1) and{[Cd(bbbm) (H2O)4] · (p-FcC6H4SO3)2(CH3OH)}n(2)(Fc = ferrocene; btmb = 1,4-bis(triazol-1-ylmethyl)- benzene); bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole), were synthesized as cocrystals and characterized by single crystal X-ray diffraction, elemental analysis and IR spectrum. In 1, two btmb molecules link Co(II) ions into one 1D double-stranded chain of loops, and these chains are bridged by Fc(SO3)22- ligands through H-bonds, resulting in an infinite 2D sandwich-type network. In 2, two adjacent Cd(II) ions are interconnected by bbbm to generate a 1D zigzag chain structure, and p FcC6H4SO3- squeezes like a wedge into the adjacent chains, further being assembled by O-H . . . O hydrogen bonds and - stacking interactions to form a 2D supramolecular network.",

keywords = "Cocrystal, Coordination polymer, Electrochemistry, H-bond, Sulfonates",

author = "Shengli Huang and Hongwei Hou and Liwei Mi and Yaoting Fan",

year = "2009",

month = jun,

doi = "10.1080/00958970902741269",

language = "English",

volume = "62",

pages = "1964--1971",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "12",

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T1 - Enforced 2D supramolecular structures within hydrogen-bonded molecular cocrystals

AU - Huang, Shengli

AU - Hou, Hongwei

AU - Mi, Liwei

AU - Fan, Yaoting

PY - 2009/6

Y1 - 2009/6

N2 - Two new coordination polymers,{[Co(btmb)2(H2O)2](Fc(SO3)2)}n(1) and{[Cd(bbbm) (H2O)4] · (p-FcC6H4SO3)2(CH3OH)}n(2)(Fc = ferrocene; btmb = 1,4-bis(triazol-1-ylmethyl)- benzene); bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole), were synthesized as cocrystals and characterized by single crystal X-ray diffraction, elemental analysis and IR spectrum. In 1, two btmb molecules link Co(II) ions into one 1D double-stranded chain of loops, and these chains are bridged by Fc(SO3)22- ligands through H-bonds, resulting in an infinite 2D sandwich-type network. In 2, two adjacent Cd(II) ions are interconnected by bbbm to generate a 1D zigzag chain structure, and p FcC6H4SO3- squeezes like a wedge into the adjacent chains, further being assembled by O-H . . . O hydrogen bonds and - stacking interactions to form a 2D supramolecular network.

AB - Two new coordination polymers,{[Co(btmb)2(H2O)2](Fc(SO3)2)}n(1) and{[Cd(bbbm) (H2O)4] · (p-FcC6H4SO3)2(CH3OH)}n(2)(Fc = ferrocene; btmb = 1,4-bis(triazol-1-ylmethyl)- benzene); bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole), were synthesized as cocrystals and characterized by single crystal X-ray diffraction, elemental analysis and IR spectrum. In 1, two btmb molecules link Co(II) ions into one 1D double-stranded chain of loops, and these chains are bridged by Fc(SO3)22- ligands through H-bonds, resulting in an infinite 2D sandwich-type network. In 2, two adjacent Cd(II) ions are interconnected by bbbm to generate a 1D zigzag chain structure, and p FcC6H4SO3- squeezes like a wedge into the adjacent chains, further being assembled by O-H . . . O hydrogen bonds and - stacking interactions to form a 2D supramolecular network.

KW - Cocrystal

KW - Coordination polymer

KW - Electrochemistry

KW - H-bond

KW - Sulfonates

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U2 - 10.1080/00958970902741269

DO - 10.1080/00958970902741269

M3 - Article

AN - SCOPUS:69849101581

SN - 0095-8972

VL - 62

SP - 1964

EP - 1971

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 12

ER -

Enforced 2D supramolecular structures within hydrogen-bonded molecular cocrystals

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