Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al4P5O19 (OH)] [C6H18N2] and [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5

Tao Tian; Yi Li; Wen Fu Yan; Ji Hong Yu; Ru Ren Xu

Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al₄P₅O₁₉ (OH)] [C₆H₁₈N₂] and [Ga₈P₈O₃₂F_5.5] [C₆H₁₈N₂]₂ [H₃O⁺]_1.5

Tao Tian, Yi Li, Wen Fu Yan^*, Ji Hong Yu, Ru Ren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new three-dimensional open-framework aluminophosphate [Al₄P₅O₁₉ (OH)] [C₆H₁₈N₂] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga₈P₈O₃₂F_5.5] [C₆H₁₈N₂]₂ [H₃O⁺]_1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.

Original language	English
Pages (from-to)	577-583
Number of pages	7
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	32
Issue number	3
Publication status	Published - Mar 2011
Externally published	Yes

Keywords

Chiral separation
Hydrothermal synthesis
Open-framework
Phosphate

Cite this

@article{787bea01ccbd4600aaf4522dd1d2f32d,

title = "Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al4P5O19 (OH)] [C6H18N2] and [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5",

abstract = "A new three-dimensional open-framework aluminophosphate [Al4P5O19 (OH)] [C6H18N2] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.",

keywords = "Chiral separation, Hydrothermal synthesis, Open-framework, Phosphate",

author = "Tao Tian and Yi Li and Yan, {Wen Fu} and Yu, {Ji Hong} and Xu, {Ru Ren}",

year = "2011",

month = mar,

language = "English",

volume = "32",

pages = "577--583",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "3",

}

Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al₄P₅O₁₉ (OH)] [C₆H₁₈N₂] and [Ga₈P₈O₃₂F_5.5] [C₆H₁₈N₂]₂ [H₃O⁺]_1.5. / Tian, Tao; Li, Yi; Yan, Wen Fu et al.
In: Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, Vol. 32, No. 3, 03.2011, p. 577-583.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al4P5O19 (OH)] [C6H18N2] and [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5

AU - Tian, Tao

AU - Li, Yi

AU - Yan, Wen Fu

AU - Yu, Ji Hong

AU - Xu, Ru Ren

PY - 2011/3

Y1 - 2011/3

N2 - A new three-dimensional open-framework aluminophosphate [Al4P5O19 (OH)] [C6H18N2] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.

AB - A new three-dimensional open-framework aluminophosphate [Al4P5O19 (OH)] [C6H18N2] (AlPO-MPMD) and a new three-dimensional open-framework gallophosphate [Ga8P8O32F5.5] [C6H18N2]2 [H3O+]1.5 (GaPO-MPMD) were hydrothermally synthesized with 2-methyl-1, 5-pentamethylene diamine (MPMD) as structure directing agent. These compounds were characterized by single crystal and powder X-ray diffraction (XRD) analyses, TGA-DTA, solid MAS NMR analysis, optical rotation analysis, experimental and simulated vibrational circular dichroism (VCD) analysis. The results confirmed that S type of enantiomer of MPMD was preferredly included in the resulting open-framework of AlPO-MPMD and GaPO-MPMD. The in situ enantiomer (chiral) separation of organic structure directing agent under hydrothermal synthesis was achieved.

KW - Chiral separation

KW - Hydrothermal synthesis

KW - Open-framework

KW - Phosphate

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M3 - Article

AN - SCOPUS:79955723036

SN - 0251-0790

VL - 32

SP - 577

EP - 583

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 3

ER -

Enantiomer separation in the hydrothermal synthesis of anionic open-framework [Al₄P₅O₁₉ (OH)] [C₆H₁₈N₂] and [Ga₈P₈O₃₂F_5.5] [C₆H₁₈N₂]₂ [H₃O⁺]_1.5

Abstract

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