Dissolution properties of trinitrophloroglucinol dissolved in deionized water

Guo Ying Zhang; Li Yang; Zun Ning Zhou; Tong Lai Zhang; Yong Rui Tian; Sheng Sheng Wang

doi:10.3969/j.issn.1006-9941.2012.01.020

Dissolution properties of trinitrophloroglucinol dissolved in deionized water

Guo Ying Zhang^*, Li Yang, Zun Ning Zhou, Tong Lai Zhang, Yong Rui Tian, Sheng Sheng Wang

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A SETARAM C80 calorimeter was used in the experiment to measure the enthalpy of dissolution and thermodynamic properties of trinitrophloroglucinol (TNPG) dissolved in deionized water (H ₂O) at 298.15 K. The empirical formula for the enthalpy of dissolution was calculated by polynomial expressions. The fomula is: Δ _dissH _m= 106.799266-2352.19194b ^1/2+15538.58581b. The standard molar enthalpy of dissolution, the relative apparent molar dissolution enthalpy and the relative partial molar enthalpy also were obtained from the experimental data of the enthalpy of dissolution of TNPG in water. The kinetic formula was obtained. From the formula the rate constant and reaction order are deduced.

Original language	English
Pages (from-to)	83-85
Number of pages	3
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	20
Issue number	1
DOIs	https://doi.org/10.3969/j.issn.1006-9941.2012.01.020
Publication status	Published - Feb 2012

Keywords

Enthalpy of solution
Microcalorimeter
Physical chemistry
Thermochemistry
Thermodynamics
Trinitrophloroglucinol (TNPG)

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10.3969/j.issn.1006-9941.2012.01.020

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title = "Dissolution properties of trinitrophloroglucinol dissolved in deionized water",

abstract = "A SETARAM C80 calorimeter was used in the experiment to measure the enthalpy of dissolution and thermodynamic properties of trinitrophloroglucinol (TNPG) dissolved in deionized water (H 2O) at 298.15 K. The empirical formula for the enthalpy of dissolution was calculated by polynomial expressions. The fomula is: Δ dissH m= 106.799266-2352.19194b 1/2+15538.58581b. The standard molar enthalpy of dissolution, the relative apparent molar dissolution enthalpy and the relative partial molar enthalpy also were obtained from the experimental data of the enthalpy of dissolution of TNPG in water. The kinetic formula was obtained. From the formula the rate constant and reaction order are deduced.",

keywords = "Enthalpy of solution, Microcalorimeter, Physical chemistry, Thermochemistry, Thermodynamics, Trinitrophloroglucinol (TNPG)",

author = "Zhang, {Guo Ying} and Li Yang and Zhou, {Zun Ning} and Zhang, {Tong Lai} and Tian, {Yong Rui} and Wang, {Sheng Sheng}",

year = "2012",

month = feb,

doi = "10.3969/j.issn.1006-9941.2012.01.020",

language = "English",

volume = "20",

pages = "83--85",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "1",

}

TY - JOUR

T1 - Dissolution properties of trinitrophloroglucinol dissolved in deionized water

AU - Zhang, Guo Ying

AU - Yang, Li

AU - Zhou, Zun Ning

AU - Zhang, Tong Lai

AU - Tian, Yong Rui

AU - Wang, Sheng Sheng

PY - 2012/2

Y1 - 2012/2

N2 - A SETARAM C80 calorimeter was used in the experiment to measure the enthalpy of dissolution and thermodynamic properties of trinitrophloroglucinol (TNPG) dissolved in deionized water (H 2O) at 298.15 K. The empirical formula for the enthalpy of dissolution was calculated by polynomial expressions. The fomula is: Δ dissH m= 106.799266-2352.19194b 1/2+15538.58581b. The standard molar enthalpy of dissolution, the relative apparent molar dissolution enthalpy and the relative partial molar enthalpy also were obtained from the experimental data of the enthalpy of dissolution of TNPG in water. The kinetic formula was obtained. From the formula the rate constant and reaction order are deduced.

AB - A SETARAM C80 calorimeter was used in the experiment to measure the enthalpy of dissolution and thermodynamic properties of trinitrophloroglucinol (TNPG) dissolved in deionized water (H 2O) at 298.15 K. The empirical formula for the enthalpy of dissolution was calculated by polynomial expressions. The fomula is: Δ dissH m= 106.799266-2352.19194b 1/2+15538.58581b. The standard molar enthalpy of dissolution, the relative apparent molar dissolution enthalpy and the relative partial molar enthalpy also were obtained from the experimental data of the enthalpy of dissolution of TNPG in water. The kinetic formula was obtained. From the formula the rate constant and reaction order are deduced.

KW - Enthalpy of solution

KW - Microcalorimeter

KW - Physical chemistry

KW - Thermochemistry

KW - Thermodynamics

KW - Trinitrophloroglucinol (TNPG)

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U2 - 10.3969/j.issn.1006-9941.2012.01.020

DO - 10.3969/j.issn.1006-9941.2012.01.020

M3 - Article

AN - SCOPUS:84863379079

SN - 1006-9941

VL - 20

SP - 83

EP - 85

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 1

ER -

Dissolution properties of trinitrophloroglucinol dissolved in deionized water

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Keywords

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