Direct oxidation of methyl radicals in OCM process deduced from correlation of product selectivities

Zhiming Gao; Yuanyuan Ma

doi:10.1016/S1003-9953(09)60110-9

Direct oxidation of methyl radicals in OCM process deduced from correlation of product selectivities

Zhiming Gao^*, Yuanyuan Ma

^*Corresponding author for this work

Ministry of Education in China

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Abstract Selectivity of hydrogen in reaction of oxidative coupling of methane (OCM) was evaluated over the M_xO_y-BaCO₃ (M_xO_y: La₂O₃, Sm₂O ₃, MgO, CaO) catalysts. Correlation of product selectivities was thus discussed. From the correlation of product selectivities, it is revealed that the carbon oxides (CO and CO₂) were most probably formed from the direct oxidation of methyl radicals under the conditions adopted in the present work. This is also in accordance with the OCM mechanism proposed in literature.

Original language	English
Pages (from-to)	534-538
Number of pages	5
Journal	Journal of Natural Gas Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1016/S1003-9953(09)60110-9
Publication status	Published - Sept 2010
Externally published	Yes

Keywords

hydrogen
mechanism
methane
oxidative coupling
radical

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10.1016/S1003-9953(09)60110-9

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abstract = "Abstract Selectivity of hydrogen in reaction of oxidative coupling of methane (OCM) was evaluated over the MxOy-BaCO3 (MxOy: La2O3, Sm2O 3, MgO, CaO) catalysts. Correlation of product selectivities was thus discussed. From the correlation of product selectivities, it is revealed that the carbon oxides (CO and CO2) were most probably formed from the direct oxidation of methyl radicals under the conditions adopted in the present work. This is also in accordance with the OCM mechanism proposed in literature.",

keywords = "hydrogen, mechanism, methane, oxidative coupling, radical",

author = "Zhiming Gao and Yuanyuan Ma",

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AU - Gao, Zhiming

AU - Ma, Yuanyuan

PY - 2010/9

Y1 - 2010/9

N2 - Abstract Selectivity of hydrogen in reaction of oxidative coupling of methane (OCM) was evaluated over the MxOy-BaCO3 (MxOy: La2O3, Sm2O 3, MgO, CaO) catalysts. Correlation of product selectivities was thus discussed. From the correlation of product selectivities, it is revealed that the carbon oxides (CO and CO2) were most probably formed from the direct oxidation of methyl radicals under the conditions adopted in the present work. This is also in accordance with the OCM mechanism proposed in literature.

AB - Abstract Selectivity of hydrogen in reaction of oxidative coupling of methane (OCM) was evaluated over the MxOy-BaCO3 (MxOy: La2O3, Sm2O 3, MgO, CaO) catalysts. Correlation of product selectivities was thus discussed. From the correlation of product selectivities, it is revealed that the carbon oxides (CO and CO2) were most probably formed from the direct oxidation of methyl radicals under the conditions adopted in the present work. This is also in accordance with the OCM mechanism proposed in literature.

KW - hydrogen

KW - mechanism

KW - methane

KW - oxidative coupling

KW - radical

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U2 - 10.1016/S1003-9953(09)60110-9

DO - 10.1016/S1003-9953(09)60110-9

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SP - 534

EP - 538

JO - Journal of Natural Gas Chemistry

JF - Journal of Natural Gas Chemistry

IS - 5

ER -

Direct oxidation of methyl radicals in OCM process deduced from correlation of product selectivities

Abstract

Keywords

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