TY - JOUR
T1 - Density, Viscosity, and Refractive Index of Aqueous CO2-Loaded and -Unloaded Ethylaminoethanol (EAE) Solutions from 293.15 to 323.15 K for Post Combustion CO2 Capture
AU - Gao, Hongxia
AU - Gao, Ge
AU - Liu, Helei
AU - Luo, Xiao
AU - Liang, Zhiwu
AU - Idem, Raphael O.
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2017/12/14
Y1 - 2017/12/14
N2 - The physical properties of densities, viscosities, and refractive indices, which are important in kinetics and mass transfer processes were measured for aqueous CO2-loaded and -unloaded (EAE) solutions applied in CO2 absorption in the temperature range from 293.15 to 323.15 K at atmospheric pressure. Due to the limitation of the instrument and corrosive behavior with increasing concentration, the mass fractions (w1) of aqueous EAE solutions selected were: as 0.089, 0.178, 0.267, and 0.356, which correspond to the molar concentrations of 1, 2, 3, and 4 mol·L-1, respectively. The determined density, viscosity and refractive index data for binary EAE+H2O and ternary CO2+EAE+H2O systems were correlated using Weiland et al. model, Redlich-Kister equation, extended Arrhenius equation, and a new proposed empirical function. All the calculated density, viscosity, and refractive index data fitted well with experimental values at all operational conditions.
AB - The physical properties of densities, viscosities, and refractive indices, which are important in kinetics and mass transfer processes were measured for aqueous CO2-loaded and -unloaded (EAE) solutions applied in CO2 absorption in the temperature range from 293.15 to 323.15 K at atmospheric pressure. Due to the limitation of the instrument and corrosive behavior with increasing concentration, the mass fractions (w1) of aqueous EAE solutions selected were: as 0.089, 0.178, 0.267, and 0.356, which correspond to the molar concentrations of 1, 2, 3, and 4 mol·L-1, respectively. The determined density, viscosity and refractive index data for binary EAE+H2O and ternary CO2+EAE+H2O systems were correlated using Weiland et al. model, Redlich-Kister equation, extended Arrhenius equation, and a new proposed empirical function. All the calculated density, viscosity, and refractive index data fitted well with experimental values at all operational conditions.
UR - http://www.scopus.com/inward/record.url?scp=85038411001&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.7b00586
DO - 10.1021/acs.jced.7b00586
M3 - Article
AN - SCOPUS:85038411001
SN - 0021-9568
VL - 62
SP - 4205
EP - 4214
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 12
ER -