TY - JOUR
T1 - Curing kinetics of 4,4′-Methylenebis epoxy and m-Xylylenediamine
AU - Li, Z. R.
AU - Li, X. D.
AU - Guo, X. Y.
N1 - Publisher Copyright:
© 2017 Published under licence by IOP Publishing Ltd.
PY - 2017/11/29
Y1 - 2017/11/29
N2 - In this paper, the curing kinetics of 4,4′-Methylenebis epoxy resin(TGDDM) and m-Xylylenediamine(m-XDA) was investigated by non-isothermal differential scanning calorimetry(DSC) at various heating rates. Selected non-isothermal methods for analyzing curing kinetics were compared. The activation energy(E) and the correlation coefficient(R) were obtained by different isoconversional methods. The reaction order(n) was obtained by the activation energy in different isoconversional methods for the by Crane equation. The results show that the apparent activation energy are 65.23kJ/mol, 52.20 kJ/mol and 66.10 kJ/mol by using the method of Kissinger, Friedman and F-W-O, the reaction order are 0.911, 0.729 and 0.923 by using the method of Kissinger, Friedman and F-W-O.
AB - In this paper, the curing kinetics of 4,4′-Methylenebis epoxy resin(TGDDM) and m-Xylylenediamine(m-XDA) was investigated by non-isothermal differential scanning calorimetry(DSC) at various heating rates. Selected non-isothermal methods for analyzing curing kinetics were compared. The activation energy(E) and the correlation coefficient(R) were obtained by different isoconversional methods. The reaction order(n) was obtained by the activation energy in different isoconversional methods for the by Crane equation. The results show that the apparent activation energy are 65.23kJ/mol, 52.20 kJ/mol and 66.10 kJ/mol by using the method of Kissinger, Friedman and F-W-O, the reaction order are 0.911, 0.729 and 0.923 by using the method of Kissinger, Friedman and F-W-O.
UR - http://www.scopus.com/inward/record.url?scp=85038375615&partnerID=8YFLogxK
U2 - 10.1088/1757-899X/265/1/012002
DO - 10.1088/1757-899X/265/1/012002
M3 - Conference article
AN - SCOPUS:85038375615
SN - 1757-8981
VL - 265
JO - IOP Conference Series: Materials Science and Engineering
JF - IOP Conference Series: Materials Science and Engineering
IS - 1
M1 - 012002
T2 - 2017 International Conference on Material Engineering and Manufacturing, ICMEM 2017
Y2 - 9 October 2017 through 11 October 2017
ER -