[Cu(en)2]0.5[Al3P3O 12(OH)]-aluminophosphate with zeotype AWO: Synthesis, crystal structure and phase transformation

Fangzheng Duan; Jiyang Li; Wei Sun; Peng Chen; Jihong Yu; Ruren Xu

doi:10.1007/s11426-010-4100-2

[Cu(en)₂]_0.5[Al₃P₃O ₁₂(OH)]-aluminophosphate with zeotype AWO: Synthesis, crystal structure and phase transformation

Fangzheng Duan, Jiyang Li, Wei Sun, Peng Chen, Jihong Yu^*, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A new aluminophosphate [Cu(en)₂]_0.5[Al ₃P₃O₁₂(OH)] (denoted as AlPO-CJ53; en = ethylenediamine) with zeotype AWO topology has been synthesized under hydrothermal conditions in which the self-assembled Cu(en) ₂ ²⁺ cations in the reaction system act as the template. AlPO-CJ53 crystallizes in the monoclinic space group P2₁/n (No. 14) with a = 0.85547(11) nm, b = 1.7671(2) nm, c = 0.90500(12) nm, β = 107.725(2)°, V = 1.3031(3) nm³. Its framework consists of AlO₄(OH)/ AlO₄ and PO₄ units forming 8-ring channels along the c direction, where the copper complex cations Cu(en) ₂ ²⁺ are located to neutralize the negative charges of the framework. AlPO-CJ53 transforms to AlPO₄-25 with zeotype ATV upon calcination at 400 °C.

Original language	English
Pages (from-to)	2159-2163
Number of pages	5
Journal	Science China Chemistry
Volume	53
Issue number	10
DOIs	https://doi.org/10.1007/s11426-010-4100-2
Publication status	Published - Oct 2010
Externally published	Yes

Keywords

aluminophosphate
copper complex
phase transformation
synthesis
zeolite

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10.1007/s11426-010-4100-2

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Duan, F., Li, J., Sun, W., Chen, P., Yu, J., & Xu, R. (2010). [Cu(en)₂]_0.5[Al₃P₃O ₁₂(OH)]-aluminophosphate with zeotype AWO: Synthesis, crystal structure and phase transformation. Science China Chemistry, 53(10), 2159-2163. https://doi.org/10.1007/s11426-010-4100-2

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title = "[Cu(en)2]0.5[Al3P3O 12(OH)]-aluminophosphate with zeotype AWO: Synthesis, crystal structure and phase transformation",

abstract = "A new aluminophosphate [Cu(en)2]0.5[Al 3P3O12(OH)] (denoted as AlPO-CJ53; en = ethylenediamine) with zeotype AWO topology has been synthesized under hydrothermal conditions in which the self-assembled Cu(en) 2 2+ cations in the reaction system act as the template. AlPO-CJ53 crystallizes in the monoclinic space group P21/n (No. 14) with a = 0.85547(11) nm, b = 1.7671(2) nm, c = 0.90500(12) nm, β = 107.725(2)°, V = 1.3031(3) nm3. Its framework consists of AlO4(OH)/ AlO4 and PO4 units forming 8-ring channels along the c direction, where the copper complex cations Cu(en) 2 2+ are located to neutralize the negative charges of the framework. AlPO-CJ53 transforms to AlPO4-25 with zeotype ATV upon calcination at 400 °C.",

keywords = "aluminophosphate, copper complex, phase transformation, synthesis, zeolite",

author = "Fangzheng Duan and Jiyang Li and Wei Sun and Peng Chen and Jihong Yu and Ruren Xu",

year = "2010",

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T1 - [Cu(en)2]0.5[Al3P3O 12(OH)]-aluminophosphate with zeotype AWO

T2 - Synthesis, crystal structure and phase transformation

AU - Duan, Fangzheng

AU - Li, Jiyang

AU - Sun, Wei

AU - Chen, Peng

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2010/10

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N2 - A new aluminophosphate [Cu(en)2]0.5[Al 3P3O12(OH)] (denoted as AlPO-CJ53; en = ethylenediamine) with zeotype AWO topology has been synthesized under hydrothermal conditions in which the self-assembled Cu(en) 2 2+ cations in the reaction system act as the template. AlPO-CJ53 crystallizes in the monoclinic space group P21/n (No. 14) with a = 0.85547(11) nm, b = 1.7671(2) nm, c = 0.90500(12) nm, β = 107.725(2)°, V = 1.3031(3) nm3. Its framework consists of AlO4(OH)/ AlO4 and PO4 units forming 8-ring channels along the c direction, where the copper complex cations Cu(en) 2 2+ are located to neutralize the negative charges of the framework. AlPO-CJ53 transforms to AlPO4-25 with zeotype ATV upon calcination at 400 °C.

AB - A new aluminophosphate [Cu(en)2]0.5[Al 3P3O12(OH)] (denoted as AlPO-CJ53; en = ethylenediamine) with zeotype AWO topology has been synthesized under hydrothermal conditions in which the self-assembled Cu(en) 2 2+ cations in the reaction system act as the template. AlPO-CJ53 crystallizes in the monoclinic space group P21/n (No. 14) with a = 0.85547(11) nm, b = 1.7671(2) nm, c = 0.90500(12) nm, β = 107.725(2)°, V = 1.3031(3) nm3. Its framework consists of AlO4(OH)/ AlO4 and PO4 units forming 8-ring channels along the c direction, where the copper complex cations Cu(en) 2 2+ are located to neutralize the negative charges of the framework. AlPO-CJ53 transforms to AlPO4-25 with zeotype ATV upon calcination at 400 °C.

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KW - copper complex

KW - phase transformation

KW - synthesis

KW - zeolite

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[Cu(en)₂]_0.5[Al₃P₃O ₁₂(OH)]-aluminophosphate with zeotype AWO: Synthesis, crystal structure and phase transformation

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