(C6H17N3)[Zn4(PO 4)2(HPO3)2]: A new layered zinc phosphate-phosphite templated by 1-(2-Aminoethyl) piperazine

Xiaoxin Chen; Yu Wang; Jihong Yu; Yongchun Zou; Ruren Xu

doi:10.1016/j.jssc.2004.03.039

(C₆H₁₇N₃)[Zn₄(PO ₄)₂(HPO₃)₂]: A new layered zinc phosphate-phosphite templated by 1-(2-Aminoethyl) piperazine

Xiaoxin Chen, Yu Wang, Jihong Yu^*, Yongchun Zou, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate-phosphite (C₆H₁₇N ₃)[Zn₄(PO₄)₂(HPO₃) ₂] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a=5.3272(11)Å, b=17.146(3)Å, c=22.071(4)Å, β=94.58(3)°, V=2009.5(7)Å³, Z=4, R₁=0.0201 (I>2σ(I)) and wR₂=0.0812 (all data). The inorganic network is based on strictly alternating ZnO₄ tetrahedral units and P-centered units including PO₄ tetrahedra and HPO₃ pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds.

Original language	English
Pages (from-to)	2518-2522
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	7
DOIs	https://doi.org/10.1016/j.jssc.2004.03.039
Publication status	Published - Jul 2004
Externally published	Yes

Keywords

Host-guest system
Hydrothermal synthesis
Layer
Structure
Zinc phosphate-phosphite

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10.1016/j.jssc.2004.03.039

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title = "(C6H17N3)[Zn4(PO 4)2(HPO3)2]: A new layered zinc phosphate-phosphite templated by 1-(2-Aminoethyl) piperazine",

abstract = "Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate-phosphite (C6H17N 3)[Zn4(PO4)2(HPO3) 2] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a=5.3272(11){\AA}, b=17.146(3){\AA}, c=22.071(4){\AA}, β=94.58(3)°, V=2009.5(7){\AA}3, Z=4, R1=0.0201 (I>2σ(I)) and wR2=0.0812 (all data). The inorganic network is based on strictly alternating ZnO4 tetrahedral units and P-centered units including PO4 tetrahedra and HPO3 pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds.",

keywords = "Host-guest system, Hydrothermal synthesis, Layer, Structure, Zinc phosphate-phosphite",

author = "Xiaoxin Chen and Yu Wang and Jihong Yu and Yongchun Zou and Ruren Xu",

year = "2004",

month = jul,

doi = "10.1016/j.jssc.2004.03.039",

language = "English",

volume = "177",

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journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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TY - JOUR

T1 - (C6H17N3)[Zn4(PO 4)2(HPO3)2]

T2 - A new layered zinc phosphate-phosphite templated by 1-(2-Aminoethyl) piperazine

AU - Chen, Xiaoxin

AU - Wang, Yu

AU - Yu, Jihong

AU - Zou, Yongchun

AU - Xu, Ruren

PY - 2004/7

Y1 - 2004/7

N2 - Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate-phosphite (C6H17N 3)[Zn4(PO4)2(HPO3) 2] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a=5.3272(11)Å, b=17.146(3)Å, c=22.071(4)Å, β=94.58(3)°, V=2009.5(7)Å3, Z=4, R1=0.0201 (I>2σ(I)) and wR2=0.0812 (all data). The inorganic network is based on strictly alternating ZnO4 tetrahedral units and P-centered units including PO4 tetrahedra and HPO3 pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds.

AB - Employing 1-(2-Aminoethyl) piperazine as a template, a new organically templated layered zinc phosphate-phosphite (C6H17N 3)[Zn4(PO4)2(HPO3) 2] has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group Cc with a=5.3272(11)Å, b=17.146(3)Å, c=22.071(4)Å, β=94.58(3)°, V=2009.5(7)Å3, Z=4, R1=0.0201 (I>2σ(I)) and wR2=0.0812 (all data). The inorganic network is based on strictly alternating ZnO4 tetrahedral units and P-centered units including PO4 tetrahedra and HPO3 pseudo-pyramids forming a double layered structure that contains columns of double six-membered rings. The diprotonated 1-(2-Aminoethyl) piperazine molecules reside in the interlayer region and interact with the inorganic network through H-bonds.

KW - Host-guest system

KW - Hydrothermal synthesis

KW - Layer

KW - Structure

KW - Zinc phosphate-phosphite

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DO - 10.1016/j.jssc.2004.03.039

M3 - Article

AN - SCOPUS:2942694205

SN - 0022-4596

VL - 177

SP - 2518

EP - 2522

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ER -

(C₆H₁₇N₃)[Zn₄(PO ₄)₂(HPO₃)₂]: A new layered zinc phosphate-phosphite templated by 1-(2-Aminoethyl) piperazine

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