[C4N2H12]2[In3(HPO4)5(H2PO4)F2]: The first 2-D fluorinated indium phosphate with double-sheet layers and 8-ring channels

Jiyang Li, Li Li, Jihong Yu*, Ruren Xu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

A new structure type of layered fluorinated indium phosphate with In/P ratio of 1/2, [C4N2H12]2[In3(HPO4)5(H2PO4)F2] (1), has been hydrothermally synthesized in the presence of piperazine as the structure directing agent. Its structure is built up from In-centered octahedra (InO4F2 and InO5F) and P-centered tetrahedra (PO3(OH), PO2(OH)({double bond, long}O) and PO(OH)2({double bond, long}O)), forming the unique double-sheet inorganic layers with 8-ring channels along the [0 1 0] directions.

Original languageEnglish
Pages (from-to)624-627
Number of pages4
JournalInorganic Chemistry Communications
Volume9
Issue number6
DOIs
Publication statusPublished - Jun 2006
Externally publishedYes

Keywords

  • 8-ring channel
  • Double-sheet layer
  • Fluorinated indium phosphate
  • Hydrothermal synthesis

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