Abstract
Morphological changes with decreasing relative humidity (RH) of supersaturated sea-salt aerosol droplets on a quartz substrate were observed using a high-speed video-camera. Stable gypsum (CaSO 4·2H 2O) or the metastable hemihydrate (CaSO 4·0.5H 2O) were precipitated as the RH decreased. The dynamic process of crystal growth under steady-state humidity was studied by controlling the RH; the metastable hemihydrate was precipitated at 70.5%-77.1% RH, and the apparent crystal growth rate was between 1.42 and 2.33 μm 3/s. Stable gypsum was formed at 80.7%-82.2% RH, and the apparent crystal growth rate was between 0.70 and 0.81 μm 3/s.
Original language | English |
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Pages (from-to) | 591-594 |
Number of pages | 4 |
Journal | Chinese Science Bulletin |
Volume | 57 |
Issue number | 6 |
DOIs | |
Publication status | Published - Feb 2012 |
Keywords
- crystallization dynamics
- high-speed photography
- sea-salt aerosols