Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation

Miao Li; Yu Qi Shi; Xinye Gan; Longbin Su; Jialin Liang; Huiqi Wu; Yiting You; Meizi Che; Peiyang Su; Tun Wu; Zhe Zhang; Wei Zhang; Liao Yuan Yao; Pingshan Wang; Ting Zheng Xie

doi:10.1021/acs.inorgchem.2c03999

Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation

Miao Li, Yu Qi Shi, Xinye Gan, Longbin Su, Jialin Liang, Huiqi Wu, Yiting You, Meizi Che, Peiyang Su, Tun Wu, Zhe Zhang, Wei Zhang, Liao Yuan Yao, Pingshan Wang^*, Ting Zheng Xie^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Guangzhou University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A coordination-driven host has been reported to encapsulate guests by noncovalent interactions. Herein, we present the design and synthesis of a new type of prism combining porphyrin and terpyridine moieties with a long cavity. The prism host can contain bisite or monosite guests through axial coordination binding of porphyrin and aromatic π interactions of terpyridine. The ligands and prismatic complexes were characterized by electrospray ionization mass spectrometry (ESI-MS), TWIM-MS, NMR spectrometry, and single-crystal X-ray diffraction analysis. The guest encapsulation was investigated through ESI-MS, NMR spectrometry, and transient absorption spectroscopy analysis. The binding constant and stability were determined by UV-Vis spectrometry and gradient tandem MS (gMS²) techniques. Based on the prism, a selectively confined condensation reaction was also performed and detected by NMR spectrometry. This study provides a new type of porphyrin- and terpyridine-based host that could be used for the detection of pyridyl- and amine-contained molecules and confined catalysis.

Original language	English
Pages (from-to)	4393-4398
Number of pages	6
Journal	Inorganic Chemistry
Volume	62
Issue number	11
DOIs	https://doi.org/10.1021/acs.inorgchem.2c03999
Publication status	Published - 20 Mar 2023

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title = "Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation",

abstract = "A coordination-driven host has been reported to encapsulate guests by noncovalent interactions. Herein, we present the design and synthesis of a new type of prism combining porphyrin and terpyridine moieties with a long cavity. The prism host can contain bisite or monosite guests through axial coordination binding of porphyrin and aromatic π interactions of terpyridine. The ligands and prismatic complexes were characterized by electrospray ionization mass spectrometry (ESI-MS), TWIM-MS, NMR spectrometry, and single-crystal X-ray diffraction analysis. The guest encapsulation was investigated through ESI-MS, NMR spectrometry, and transient absorption spectroscopy analysis. The binding constant and stability were determined by UV-Vis spectrometry and gradient tandem MS (gMS2) techniques. Based on the prism, a selectively confined condensation reaction was also performed and detected by NMR spectrometry. This study provides a new type of porphyrin- and terpyridine-based host that could be used for the detection of pyridyl- and amine-contained molecules and confined catalysis.",

author = "Miao Li and Shi, {Yu Qi} and Xinye Gan and Longbin Su and Jialin Liang and Huiqi Wu and Yiting You and Meizi Che and Peiyang Su and Tun Wu and Zhe Zhang and Wei Zhang and Yao, {Liao Yuan} and Pingshan Wang and Xie, {Ting Zheng}",

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doi = "10.1021/acs.inorgchem.2c03999",

language = "English",

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T1 - Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation

AU - Li, Miao

AU - Shi, Yu Qi

AU - Gan, Xinye

AU - Su, Longbin

AU - Liang, Jialin

AU - Wu, Huiqi

AU - You, Yiting

AU - Che, Meizi

AU - Su, Peiyang

AU - Wu, Tun

AU - Zhang, Zhe

AU - Zhang, Wei

AU - Yao, Liao Yuan

AU - Wang, Pingshan

AU - Xie, Ting Zheng

PY - 2023/3/20

Y1 - 2023/3/20

N2 - A coordination-driven host has been reported to encapsulate guests by noncovalent interactions. Herein, we present the design and synthesis of a new type of prism combining porphyrin and terpyridine moieties with a long cavity. The prism host can contain bisite or monosite guests through axial coordination binding of porphyrin and aromatic π interactions of terpyridine. The ligands and prismatic complexes were characterized by electrospray ionization mass spectrometry (ESI-MS), TWIM-MS, NMR spectrometry, and single-crystal X-ray diffraction analysis. The guest encapsulation was investigated through ESI-MS, NMR spectrometry, and transient absorption spectroscopy analysis. The binding constant and stability were determined by UV-Vis spectrometry and gradient tandem MS (gMS2) techniques. Based on the prism, a selectively confined condensation reaction was also performed and detected by NMR spectrometry. This study provides a new type of porphyrin- and terpyridine-based host that could be used for the detection of pyridyl- and amine-contained molecules and confined catalysis.

AB - A coordination-driven host has been reported to encapsulate guests by noncovalent interactions. Herein, we present the design and synthesis of a new type of prism combining porphyrin and terpyridine moieties with a long cavity. The prism host can contain bisite or monosite guests through axial coordination binding of porphyrin and aromatic π interactions of terpyridine. The ligands and prismatic complexes were characterized by electrospray ionization mass spectrometry (ESI-MS), TWIM-MS, NMR spectrometry, and single-crystal X-ray diffraction analysis. The guest encapsulation was investigated through ESI-MS, NMR spectrometry, and transient absorption spectroscopy analysis. The binding constant and stability were determined by UV-Vis spectrometry and gradient tandem MS (gMS2) techniques. Based on the prism, a selectively confined condensation reaction was also performed and detected by NMR spectrometry. This study provides a new type of porphyrin- and terpyridine-based host that could be used for the detection of pyridyl- and amine-contained molecules and confined catalysis.

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DO - 10.1021/acs.inorgchem.2c03999

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SN - 0020-1669

VL - 62

SP - 4393

EP - 4398

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation

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