Li, M., Shi, Y. Q., Gan, X., Su, L., Liang, J., Wu, H., You, Y., Che, M., Su, P., Wu, T., Zhang, Z., Zhang, W., Yao, L. Y., Wang, P., & Xie, T. Z. (2023). Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation. Inorganic Chemistry, 62(11), 4393-4398. https://doi.org/10.1021/acs.inorgchem.2c03999
Li, Miao ; Shi, Yu Qi ; Gan, Xinye et al. / Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation. In: Inorganic Chemistry. 2023 ; Vol. 62, No. 11. pp. 4393-4398.
@article{4d84b557ea054f8d99e63c9839f0c8fe,
title = "Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation",
abstract = "A coordination-driven host has been reported to encapsulate guests by noncovalent interactions. Herein, we present the design and synthesis of a new type of prism combining porphyrin and terpyridine moieties with a long cavity. The prism host can contain bisite or monosite guests through axial coordination binding of porphyrin and aromatic π interactions of terpyridine. The ligands and prismatic complexes were characterized by electrospray ionization mass spectrometry (ESI-MS), TWIM-MS, NMR spectrometry, and single-crystal X-ray diffraction analysis. The guest encapsulation was investigated through ESI-MS, NMR spectrometry, and transient absorption spectroscopy analysis. The binding constant and stability were determined by UV-Vis spectrometry and gradient tandem MS (gMS2) techniques. Based on the prism, a selectively confined condensation reaction was also performed and detected by NMR spectrometry. This study provides a new type of porphyrin- and terpyridine-based host that could be used for the detection of pyridyl- and amine-contained molecules and confined catalysis.",
author = "Miao Li and Shi, {Yu Qi} and Xinye Gan and Longbin Su and Jialin Liang and Huiqi Wu and Yiting You and Meizi Che and Peiyang Su and Tun Wu and Zhe Zhang and Wei Zhang and Yao, {Liao Yuan} and Pingshan Wang and Xie, {Ting Zheng}",
note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",
year = "2023",
month = mar,
day = "20",
doi = "10.1021/acs.inorgchem.2c03999",
language = "English",
volume = "62",
pages = "4393--4398",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "11",
}
Li, M, Shi, YQ, Gan, X, Su, L, Liang, J, Wu, H, You, Y, Che, M, Su, P, Wu, T, Zhang, Z, Zhang, W, Yao, LY, Wang, P & Xie, TZ 2023, 'Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation', Inorganic Chemistry, vol. 62, no. 11, pp. 4393-4398. https://doi.org/10.1021/acs.inorgchem.2c03999
Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation. / Li, Miao; Shi, Yu Qi; Gan, Xinye et al.
In:
Inorganic Chemistry, Vol. 62, No. 11, 20.03.2023, p. 4393-4398.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation
AU - Li, Miao
AU - Shi, Yu Qi
AU - Gan, Xinye
AU - Su, Longbin
AU - Liang, Jialin
AU - Wu, Huiqi
AU - You, Yiting
AU - Che, Meizi
AU - Su, Peiyang
AU - Wu, Tun
AU - Zhang, Zhe
AU - Zhang, Wei
AU - Yao, Liao Yuan
AU - Wang, Pingshan
AU - Xie, Ting Zheng
N1 - Publisher Copyright:
© 2023 American Chemical Society.
PY - 2023/3/20
Y1 - 2023/3/20
N2 - A coordination-driven host has been reported to encapsulate guests by noncovalent interactions. Herein, we present the design and synthesis of a new type of prism combining porphyrin and terpyridine moieties with a long cavity. The prism host can contain bisite or monosite guests through axial coordination binding of porphyrin and aromatic π interactions of terpyridine. The ligands and prismatic complexes were characterized by electrospray ionization mass spectrometry (ESI-MS), TWIM-MS, NMR spectrometry, and single-crystal X-ray diffraction analysis. The guest encapsulation was investigated through ESI-MS, NMR spectrometry, and transient absorption spectroscopy analysis. The binding constant and stability were determined by UV-Vis spectrometry and gradient tandem MS (gMS2) techniques. Based on the prism, a selectively confined condensation reaction was also performed and detected by NMR spectrometry. This study provides a new type of porphyrin- and terpyridine-based host that could be used for the detection of pyridyl- and amine-contained molecules and confined catalysis.
AB - A coordination-driven host has been reported to encapsulate guests by noncovalent interactions. Herein, we present the design and synthesis of a new type of prism combining porphyrin and terpyridine moieties with a long cavity. The prism host can contain bisite or monosite guests through axial coordination binding of porphyrin and aromatic π interactions of terpyridine. The ligands and prismatic complexes were characterized by electrospray ionization mass spectrometry (ESI-MS), TWIM-MS, NMR spectrometry, and single-crystal X-ray diffraction analysis. The guest encapsulation was investigated through ESI-MS, NMR spectrometry, and transient absorption spectroscopy analysis. The binding constant and stability were determined by UV-Vis spectrometry and gradient tandem MS (gMS2) techniques. Based on the prism, a selectively confined condensation reaction was also performed and detected by NMR spectrometry. This study provides a new type of porphyrin- and terpyridine-based host that could be used for the detection of pyridyl- and amine-contained molecules and confined catalysis.
UR - http://www.scopus.com/inward/record.url?scp=85149766521&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.2c03999
DO - 10.1021/acs.inorgchem.2c03999
M3 - Article
C2 - 36892430
AN - SCOPUS:85149766521
SN - 0020-1669
VL - 62
SP - 4393
EP - 4398
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 11
ER -
Li M, Shi YQ, Gan X, Su L, Liang J, Wu H et al. Coordination-Driven Tetragonal Prismatic Cage and the Investigation on Host-Guest Complexation. Inorganic Chemistry. 2023 Mar 20;62(11):4393-4398. doi: 10.1021/acs.inorgchem.2c03999