Construction of two novel coordination polymers from a V-shaped bisimidazole ligand: Synthesis, characterization and properties

Xianmin Guo; Yongnian Yan; Huadong Guo; Nan Wang; Yanjuan Qi

doi:10.1016/j.inoche.2015.12.020

Construction of two novel coordination polymers from a V-shaped bisimidazole ligand: Synthesis, characterization and properties

Xianmin Guo^*, Yongnian Yan, Huadong Guo, Nan Wang, Yanjuan Qi

^*Corresponding author for this work

Changchun Normal University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Two novel coordination polymers, [Cd₂(cdc)₂(bmis)₂] (1) and [Zn₆(cdc)₄(OH)₄(bmis)₄]·2H₂O·4DMF (2) (bmis = bis(4-(2′-methylimidazol-ylphenyl)sulfone, H₂cdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized. Compound 1 features an interesting usf net presenting the alternate arrangement of the single- and triple-stranded helices. Compound 2 exhibits an unusual two-fold interpenetrating polyrotaxane motif composed of two interlocked sets of identical pcu nets. In addition, their photoluminescent properties have also been evaluated.

Original language	English
Pages (from-to)	59-62
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	64
DOIs	https://doi.org/10.1016/j.inoche.2015.12.020
Publication status	Published - 1 Feb 2016
Externally published	Yes

Keywords

Coordination polymers
Helice
Luminescence
Polyrotaxane

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10.1016/j.inoche.2015.12.020

Cite this

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title = "Construction of two novel coordination polymers from a V-shaped bisimidazole ligand: Synthesis, characterization and properties",

abstract = "Two novel coordination polymers, [Cd2(cdc)2(bmis)2] (1) and [Zn6(cdc)4(OH)4(bmis)4]·2H2O·4DMF (2) (bmis = bis(4-(2′-methylimidazol-ylphenyl)sulfone, H2cdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized. Compound 1 features an interesting usf net presenting the alternate arrangement of the single- and triple-stranded helices. Compound 2 exhibits an unusual two-fold interpenetrating polyrotaxane motif composed of two interlocked sets of identical pcu nets. In addition, their photoluminescent properties have also been evaluated.",

keywords = "Coordination polymers, Helice, Luminescence, Polyrotaxane",

author = "Xianmin Guo and Yongnian Yan and Huadong Guo and Nan Wang and Yanjuan Qi",

year = "2016",

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day = "1",

doi = "10.1016/j.inoche.2015.12.020",

language = "English",

volume = "64",

pages = "59--62",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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TY - JOUR

T1 - Construction of two novel coordination polymers from a V-shaped bisimidazole ligand

T2 - Synthesis, characterization and properties

AU - Guo, Xianmin

AU - Yan, Yongnian

AU - Guo, Huadong

AU - Wang, Nan

AU - Qi, Yanjuan

PY - 2016/2/1

Y1 - 2016/2/1

N2 - Two novel coordination polymers, [Cd2(cdc)2(bmis)2] (1) and [Zn6(cdc)4(OH)4(bmis)4]·2H2O·4DMF (2) (bmis = bis(4-(2′-methylimidazol-ylphenyl)sulfone, H2cdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized. Compound 1 features an interesting usf net presenting the alternate arrangement of the single- and triple-stranded helices. Compound 2 exhibits an unusual two-fold interpenetrating polyrotaxane motif composed of two interlocked sets of identical pcu nets. In addition, their photoluminescent properties have also been evaluated.

AB - Two novel coordination polymers, [Cd2(cdc)2(bmis)2] (1) and [Zn6(cdc)4(OH)4(bmis)4]·2H2O·4DMF (2) (bmis = bis(4-(2′-methylimidazol-ylphenyl)sulfone, H2cdc = 1,4-cyclohexanedicarboxylic acid), have been synthesized and structurally characterized. Compound 1 features an interesting usf net presenting the alternate arrangement of the single- and triple-stranded helices. Compound 2 exhibits an unusual two-fold interpenetrating polyrotaxane motif composed of two interlocked sets of identical pcu nets. In addition, their photoluminescent properties have also been evaluated.

KW - Coordination polymers

KW - Helice

KW - Luminescence

KW - Polyrotaxane

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U2 - 10.1016/j.inoche.2015.12.020

DO - 10.1016/j.inoche.2015.12.020

M3 - Article

AN - SCOPUS:84953321807

SN - 1387-7003

VL - 64

SP - 59

EP - 62

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Construction of two novel coordination polymers from a V-shaped bisimidazole ligand: Synthesis, characterization and properties

Abstract

Keywords

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