Construction of Bicyclic 1,2,3-Triazine N-Oxides from Aminocyanides

Yuji Liu; Xiujuan Qi; Wenquan Zhang; Ping Yin; Ziwu Cai; Qinghua Zhang

doi:10.1021/acs.orglett.0c03952

Construction of Bicyclic 1,2,3-Triazine N-Oxides from Aminocyanides

Yuji Liu, Xiujuan Qi, Wenquan Zhang^*, Ping Yin^*, Ziwu Cai, Qinghua Zhang^*

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Using a facile and cost-effective method, nine bicyclic 1,2,3-triazine 2-oxides were synthesized from o-aminocyanide substrates through an unusual nitration cyclization. The reaction mechanism was studied experimentally and theoretically. Moreover, nine 1,2,3-triazine 3-oxides were also obtained in good yields.

Original language	English
Pages (from-to)	734-738
Number of pages	5
Journal	Organic Letters
Volume	23
Issue number	3
DOIs	https://doi.org/10.1021/acs.orglett.0c03952
Publication status	Published - 5 Feb 2021

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10.1021/acs.orglett.0c03952

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title = "Construction of Bicyclic 1,2,3-Triazine N-Oxides from Aminocyanides",

abstract = "Using a facile and cost-effective method, nine bicyclic 1,2,3-triazine 2-oxides were synthesized from o-aminocyanide substrates through an unusual nitration cyclization. The reaction mechanism was studied experimentally and theoretically. Moreover, nine 1,2,3-triazine 3-oxides were also obtained in good yields.",

author = "Yuji Liu and Xiujuan Qi and Wenquan Zhang and Ping Yin and Ziwu Cai and Qinghua Zhang",

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AU - Liu, Yuji

AU - Qi, Xiujuan

AU - Zhang, Wenquan

AU - Yin, Ping

AU - Cai, Ziwu

AU - Zhang, Qinghua

PY - 2021/2/5

Y1 - 2021/2/5

N2 - Using a facile and cost-effective method, nine bicyclic 1,2,3-triazine 2-oxides were synthesized from o-aminocyanide substrates through an unusual nitration cyclization. The reaction mechanism was studied experimentally and theoretically. Moreover, nine 1,2,3-triazine 3-oxides were also obtained in good yields.

AB - Using a facile and cost-effective method, nine bicyclic 1,2,3-triazine 2-oxides were synthesized from o-aminocyanide substrates through an unusual nitration cyclization. The reaction mechanism was studied experimentally and theoretically. Moreover, nine 1,2,3-triazine 3-oxides were also obtained in good yields.

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U2 - 10.1021/acs.orglett.0c03952

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Construction of Bicyclic 1,2,3-Triazine N-Oxides from Aminocyanides

Abstract

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