Conducting metallophthalocyanine 2D covalent organic frameworks: The role of central metals in controlling π-electronic functions

Xuesong Ding, Xiao Feng, Akinori Saeki, Shu Seki, Atsushi Nagai, Donglin Jiang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

133 Citations (Scopus)

Abstract

Phthalocyanine covalent organic frameworks with different central metals are synthesized, and the AA-stacking structure of the 2D polymer sheets results in periodic phthalocyanine π-columns. The central metals control the π-electronic functions, including the improvement of light absorbance, the ease of carrier transport, and the photocurrent gain.

Original languageEnglish
Pages (from-to)8952-8954
Number of pages3
JournalChemical Communications
Volume48
Issue number71
DOIs
Publication statusPublished - 8 Aug 2012
Externally publishedYes

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