Composition tunable ternary Pt-Ni-Co octahedra for optimized oxygen reduction activity

Zipeng Zhao; Miao Feng; Jihan Zhou; Zeyan Liu; Mufan Li; Zheng Fan; Oshton Tsen; Jianwei Miao; Xiangfeng Duan; Yu Huang

doi:10.1039/c6cc06165f

Composition tunable ternary Pt-Ni-Co octahedra for optimized oxygen reduction activity

Zipeng Zhao, Miao Feng, Jihan Zhou, Zeyan Liu, Mufan Li, Zheng Fan, Oshton Tsen, Jianwei Miao, Xiangfeng Duan, Yu Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

Herein, we report a one-step synthesis method for octahedral Pt-Ni-Co ternary catalysts with tunable compositions and fixed shapes. Impressively, the composition optimized octahedral PtNi_0.55Co_0.1/C demonstrated a significant improvement in ORR activity compared to those of previously reported Pt-Ni-Co alloy octahedra, showing an outstanding specific activity of 5.05 mA cm^-2 and a mass activity of 2.80 mA μg_Pt^-1, which are around 20.2 times and 14.7 times higher than those of the commercial Pt/C catalyst (0.25 mA cm^-2 and 0.19 mA μg_Pt^-1).

Original language	English
Pages (from-to)	11215-11218
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	75
DOIs	https://doi.org/10.1039/c6cc06165f
Publication status	Published - 2016
Externally published	Yes

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title = "Composition tunable ternary Pt-Ni-Co octahedra for optimized oxygen reduction activity",

abstract = "Herein, we report a one-step synthesis method for octahedral Pt-Ni-Co ternary catalysts with tunable compositions and fixed shapes. Impressively, the composition optimized octahedral PtNi0.55Co0.1/C demonstrated a significant improvement in ORR activity compared to those of previously reported Pt-Ni-Co alloy octahedra, showing an outstanding specific activity of 5.05 mA cm-2 and a mass activity of 2.80 mA μgPt-1, which are around 20.2 times and 14.7 times higher than those of the commercial Pt/C catalyst (0.25 mA cm-2 and 0.19 mA μgPt-1).",

author = "Zipeng Zhao and Miao Feng and Jihan Zhou and Zeyan Liu and Mufan Li and Zheng Fan and Oshton Tsen and Jianwei Miao and Xiangfeng Duan and Yu Huang",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

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language = "English",

volume = "52",

pages = "11215--11218",

journal = "Chemical Communications",

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T1 - Composition tunable ternary Pt-Ni-Co octahedra for optimized oxygen reduction activity

AU - Zhao, Zipeng

AU - Feng, Miao

AU - Zhou, Jihan

AU - Liu, Zeyan

AU - Li, Mufan

AU - Fan, Zheng

AU - Tsen, Oshton

AU - Miao, Jianwei

AU - Duan, Xiangfeng

AU - Huang, Yu

PY - 2016

Y1 - 2016

N2 - Herein, we report a one-step synthesis method for octahedral Pt-Ni-Co ternary catalysts with tunable compositions and fixed shapes. Impressively, the composition optimized octahedral PtNi0.55Co0.1/C demonstrated a significant improvement in ORR activity compared to those of previously reported Pt-Ni-Co alloy octahedra, showing an outstanding specific activity of 5.05 mA cm-2 and a mass activity of 2.80 mA μgPt-1, which are around 20.2 times and 14.7 times higher than those of the commercial Pt/C catalyst (0.25 mA cm-2 and 0.19 mA μgPt-1).

AB - Herein, we report a one-step synthesis method for octahedral Pt-Ni-Co ternary catalysts with tunable compositions and fixed shapes. Impressively, the composition optimized octahedral PtNi0.55Co0.1/C demonstrated a significant improvement in ORR activity compared to those of previously reported Pt-Ni-Co alloy octahedra, showing an outstanding specific activity of 5.05 mA cm-2 and a mass activity of 2.80 mA μgPt-1, which are around 20.2 times and 14.7 times higher than those of the commercial Pt/C catalyst (0.25 mA cm-2 and 0.19 mA μgPt-1).

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U2 - 10.1039/c6cc06165f

DO - 10.1039/c6cc06165f

M3 - Article

AN - SCOPUS:84987829326

SN - 1359-7345

VL - 52

SP - 11215

EP - 11218

JO - Chemical Communications

JF - Chemical Communications

IS - 75

ER -

Composition tunable ternary Pt-Ni-Co octahedra for optimized oxygen reduction activity

Abstract

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