TY - JOUR
T1 - [Co(en)3][In3(H2PO4) 6(HPO4)3]·H2O
T2 - A new layered indium phosphate templated by cobalt complex
AU - Du, Yu
AU - Yu, Jihong
AU - Wang, Yu
AU - Pan, Qinhe
AU - Zou, Yongcun
AU - Xu, Ruren
PY - 2004/9
Y1 - 2004/9
N2 - A new layered indium phosphate [Co(en)3][In3(H 2PO4)6(HPO4)3] ·H2O (1) has been synthesized solvothermally by using a racemic mix of chiral metal complex Co(en)3Cl3 as a template. Its structure is determined by single-crystal X-ray diffraction analysis and further characterized by X-ray powder diffraction, ICP, NMR and TG analyses. The inorganic layer is built up by alternation of In-centred octahedra (InO6) and P-centered tetrahedra (PO3(OH), PO 2(OH)2, PO2(=O)(OH) and PO(=O)(OH)2) forming a 4.12-net. The metal complex cations locate in the interlayer region and interact with the host network through H-bonds. It is the first indium phosphate compound templated by a transition-metal complex and is isostructural with GaPO-CJ14. Crystal data: 1, monoclinic, space group P21/m (No. 11), a=9.1700(18)Å, b=22.6923(5)Å, c=9.9116(2)Å, β=107.87(3)°, Z=4, R1[I>2σ(I)]=0.0287 and wR 2(all data)=0.0939.
AB - A new layered indium phosphate [Co(en)3][In3(H 2PO4)6(HPO4)3] ·H2O (1) has been synthesized solvothermally by using a racemic mix of chiral metal complex Co(en)3Cl3 as a template. Its structure is determined by single-crystal X-ray diffraction analysis and further characterized by X-ray powder diffraction, ICP, NMR and TG analyses. The inorganic layer is built up by alternation of In-centred octahedra (InO6) and P-centered tetrahedra (PO3(OH), PO 2(OH)2, PO2(=O)(OH) and PO(=O)(OH)2) forming a 4.12-net. The metal complex cations locate in the interlayer region and interact with the host network through H-bonds. It is the first indium phosphate compound templated by a transition-metal complex and is isostructural with GaPO-CJ14. Crystal data: 1, monoclinic, space group P21/m (No. 11), a=9.1700(18)Å, b=22.6923(5)Å, c=9.9116(2)Å, β=107.87(3)°, Z=4, R1[I>2σ(I)]=0.0287 and wR 2(all data)=0.0939.
KW - Indium phosphate
KW - Layer
KW - Metal complex
KW - Structure
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=4444298746&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2004.05.017
DO - 10.1016/j.jssc.2004.05.017
M3 - Article
AN - SCOPUS:4444298746
SN - 0022-4596
VL - 177
SP - 3032
EP - 3037
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 9
ER -
