Chiral layered zincophosphate [d-Co(en)3]Zn3(H 0.5PO4)2(HPO4)2 assembled about d-Co(en)33+ complex cations

Yu Wang; Peng Chen; Jiyang Li; Jihong Yu; Jin Xu; Qinhe Pan; Ruren Xu

doi:10.1021/ic0519640

Chiral layered zincophosphate [d-Co(en)₃]Zn₃(H _0.5PO₄)₂(HPO₄)₂ assembled about d-Co(en)₃³⁺ complex cations

Yu Wang, Peng Chen, Jiyang Li, Jihong Yu^*, Jin Xu, Qinhe Pan, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

A new chiral layered zincophosphate [d-Co(en)₃]Zn ₃(H_0.5PO₄)₂(HPO₄) ₂, designated ZnPO-CJ16, has been hydrothermally synthesized by using the optically pure chiral metal complex d-Co(en)₃I₃ as the template. It contains 4.6-net sheets which array in a helical fashion with an ABCDEF stacking sequence along the [001] direction. The chiral d-Co(en) ₃³⁺ complex cations reside in the interlayer regions. Interestingly, there exist symmetrical O⋯H⋯O H-bonds between inorganic sheets, which results in a pseudo-three-dimensional open-framework structure stabilized by strong H-bonds. The crystal data are as follows: ZnPO-CJ16, [d-Co(en)₃]Zn₃(H_0.5PO ₄)₂(HPO₄)₂; M = 818.26; hexagonal; P6₅22 (No. 179); a = 8.5832(12) Å; c = 52.610(11) Å; U = 3356.6(9) Å³; T = 293(2) K; Z = 6; R₁ = 0.0415 (I > 2σ(I)); wR₂ = 0.1383 (all data); Flack parameter, 0.04(4).

Original language	English
Pages (from-to)	4764-4768
Number of pages	5
Journal	Inorganic Chemistry
Volume	45
Issue number	12
DOIs	https://doi.org/10.1021/ic0519640
Publication status	Published - 12 Jun 2006
Externally published	Yes

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@article{6378f38e802849b795cbd49dc214a383,

title = "Chiral layered zincophosphate [d-Co(en)3]Zn3(H 0.5PO4)2(HPO4)2 assembled about d-Co(en)33+ complex cations",

abstract = "A new chiral layered zincophosphate [d-Co(en)3]Zn 3(H0.5PO4)2(HPO4) 2, designated ZnPO-CJ16, has been hydrothermally synthesized by using the optically pure chiral metal complex d-Co(en)3I3 as the template. It contains 4.6-net sheets which array in a helical fashion with an ABCDEF stacking sequence along the [001] direction. The chiral d-Co(en) 33+ complex cations reside in the interlayer regions. Interestingly, there exist symmetrical O⋯H⋯O H-bonds between inorganic sheets, which results in a pseudo-three-dimensional open-framework structure stabilized by strong H-bonds. The crystal data are as follows: ZnPO-CJ16, [d-Co(en)3]Zn3(H0.5PO 4)2(HPO4)2; M = 818.26; hexagonal; P6522 (No. 179); a = 8.5832(12) {\AA}; c = 52.610(11) {\AA}; U = 3356.6(9) {\AA}3; T = 293(2) K; Z = 6; R1 = 0.0415 (I > 2σ(I)); wR2 = 0.1383 (all data); Flack parameter, 0.04(4).",

author = "Yu Wang and Peng Chen and Jiyang Li and Jihong Yu and Jin Xu and Qinhe Pan and Ruren Xu",

year = "2006",

month = jun,

day = "12",

doi = "10.1021/ic0519640",

language = "English",

volume = "45",

pages = "4764--4768",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - Chiral layered zincophosphate [d-Co(en)3]Zn3(H 0.5PO4)2(HPO4)2 assembled about d-Co(en)33+ complex cations

AU - Wang, Yu

AU - Chen, Peng

AU - Li, Jiyang

AU - Yu, Jihong

AU - Xu, Jin

AU - Pan, Qinhe

AU - Xu, Ruren

PY - 2006/6/12

Y1 - 2006/6/12

N2 - A new chiral layered zincophosphate [d-Co(en)3]Zn 3(H0.5PO4)2(HPO4) 2, designated ZnPO-CJ16, has been hydrothermally synthesized by using the optically pure chiral metal complex d-Co(en)3I3 as the template. It contains 4.6-net sheets which array in a helical fashion with an ABCDEF stacking sequence along the [001] direction. The chiral d-Co(en) 33+ complex cations reside in the interlayer regions. Interestingly, there exist symmetrical O⋯H⋯O H-bonds between inorganic sheets, which results in a pseudo-three-dimensional open-framework structure stabilized by strong H-bonds. The crystal data are as follows: ZnPO-CJ16, [d-Co(en)3]Zn3(H0.5PO 4)2(HPO4)2; M = 818.26; hexagonal; P6522 (No. 179); a = 8.5832(12) Å; c = 52.610(11) Å; U = 3356.6(9) Å3; T = 293(2) K; Z = 6; R1 = 0.0415 (I > 2σ(I)); wR2 = 0.1383 (all data); Flack parameter, 0.04(4).

AB - A new chiral layered zincophosphate [d-Co(en)3]Zn 3(H0.5PO4)2(HPO4) 2, designated ZnPO-CJ16, has been hydrothermally synthesized by using the optically pure chiral metal complex d-Co(en)3I3 as the template. It contains 4.6-net sheets which array in a helical fashion with an ABCDEF stacking sequence along the [001] direction. The chiral d-Co(en) 33+ complex cations reside in the interlayer regions. Interestingly, there exist symmetrical O⋯H⋯O H-bonds between inorganic sheets, which results in a pseudo-three-dimensional open-framework structure stabilized by strong H-bonds. The crystal data are as follows: ZnPO-CJ16, [d-Co(en)3]Zn3(H0.5PO 4)2(HPO4)2; M = 818.26; hexagonal; P6522 (No. 179); a = 8.5832(12) Å; c = 52.610(11) Å; U = 3356.6(9) Å3; T = 293(2) K; Z = 6; R1 = 0.0415 (I > 2σ(I)); wR2 = 0.1383 (all data); Flack parameter, 0.04(4).

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U2 - 10.1021/ic0519640

DO - 10.1021/ic0519640

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SN - 0020-1669

VL - 45

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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ER -

Chiral layered zincophosphate [d-Co(en)₃]Zn₃(H _0.5PO₄)₂(HPO₄)₂ assembled about d-Co(en)₃³⁺ complex cations

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