Cation triggered spring-like helicates based on ketone-substituted bis-catechol ligands

Xiaofei Chen; Miriam Baumert; Roland Fröhlich; Markus Albrecht

doi:10.1007/s10847-019-00888-9

Cation triggered spring-like helicates based on ketone-substituted bis-catechol ligands

Xiaofei Chen, Miriam Baumert, Roland Fröhlich, Markus Albrecht^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The development of switchable molecular units is a challenging task of modern synthetic and supramolecular chemistry. In the present study, alkyl bridged bis(catecholketone) ligands are introduced in order to obtain helicates which cation triggered show some spring type dynamics. The preparation of the ligands as well as of the complexes and corresponding switching processes are described.

Original language	English
Pages (from-to)	133-140
Number of pages	8
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	94
Issue number	3-4
DOIs	https://doi.org/10.1007/s10847-019-00888-9
Publication status	Published - 15 Aug 2019
Externally published	Yes

Keywords

Helicate
Molecular spring
Molecular switch
Self-assembly

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10.1007/s10847-019-00888-9

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abstract = "The development of switchable molecular units is a challenging task of modern synthetic and supramolecular chemistry. In the present study, alkyl bridged bis(catecholketone) ligands are introduced in order to obtain helicates which cation triggered show some spring type dynamics. The preparation of the ligands as well as of the complexes and corresponding switching processes are described.",

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AU - Chen, Xiaofei

AU - Baumert, Miriam

AU - Fröhlich, Roland

AU - Albrecht, Markus

PY - 2019/8/15

Y1 - 2019/8/15

N2 - The development of switchable molecular units is a challenging task of modern synthetic and supramolecular chemistry. In the present study, alkyl bridged bis(catecholketone) ligands are introduced in order to obtain helicates which cation triggered show some spring type dynamics. The preparation of the ligands as well as of the complexes and corresponding switching processes are described.

AB - The development of switchable molecular units is a challenging task of modern synthetic and supramolecular chemistry. In the present study, alkyl bridged bis(catecholketone) ligands are introduced in order to obtain helicates which cation triggered show some spring type dynamics. The preparation of the ligands as well as of the complexes and corresponding switching processes are described.

KW - Helicate

KW - Molecular spring

KW - Molecular switch

KW - Self-assembly

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M3 - Article

AN - SCOPUS:85068778650

SN - 0923-0750

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JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

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ER -

Cation triggered spring-like helicates based on ketone-substituted bis-catechol ligands

Abstract

Keywords

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