|(C 6N 4H 21) 2|[Ge 7O 14F 6]: A new germanate compound constructed from alternately stacked pseudo triple-sheet layers

Xiaoyan Ren; Jiancong Liu; Yi Li; Jihong Yu

doi:10.1002/zaac.201200093

|(C ₆N ₄H ₂₁) ₂|[Ge ₇O ₁₄F ₆]: A new germanate compound constructed from alternately stacked pseudo triple-sheet layers

Xiaoyan Ren, Jiancong Liu, Yi Li^*, Jihong Yu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

Abstract

A novel layered germanate compound, |(C ₆N ₄H ₂₁) ₂|[Ge ₇O ₁₄F ₆] (JU-86, JU = Jilin University), was solvothermally synthesized. Its structure consists of 4.6-net sheets built up from dissymmetric 8 ³ building units. Different from those found in several metal phosphate compounds, half of the 4.6-net sheets in JU-86 are constructed from right-handed 8 ³ building units and the other half are constructed from left-handed ones. Right-handed and left-handed 4.6-net sheets are stacked alternately in JU-86. Each 4.6-net sheet is sandwiched by two layers of protonated tris(2-aminoethyl)amine (tren) molecules to form an unusual pseudo triple-sheet layer through hydrogen-bonding interactions. No hydrogen bonds are found between different pseudo triple-sheet layers.

Original language	English
Pages (from-to)	1362-1364
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	638
Issue number	9
DOIs	https://doi.org/10.1002/zaac.201200093
Publication status	Published - Jul 2012
Externally published	Yes

Keywords

Germanates
Handedness
Hydrogen bonds
Layered compounds
Solid-state structures

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10.1002/zaac.201200093

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title = "|(C 6N 4H 21) 2|[Ge 7O 14F 6]: A new germanate compound constructed from alternately stacked pseudo triple-sheet layers",

abstract = "A novel layered germanate compound, |(C 6N 4H 21) 2|[Ge 7O 14F 6] (JU-86, JU = Jilin University), was solvothermally synthesized. Its structure consists of 4.6-net sheets built up from dissymmetric 8 3 building units. Different from those found in several metal phosphate compounds, half of the 4.6-net sheets in JU-86 are constructed from right-handed 8 3 building units and the other half are constructed from left-handed ones. Right-handed and left-handed 4.6-net sheets are stacked alternately in JU-86. Each 4.6-net sheet is sandwiched by two layers of protonated tris(2-aminoethyl)amine (tren) molecules to form an unusual pseudo triple-sheet layer through hydrogen-bonding interactions. No hydrogen bonds are found between different pseudo triple-sheet layers.",

keywords = "Germanates, Handedness, Hydrogen bonds, Layered compounds, Solid-state structures",

author = "Xiaoyan Ren and Jiancong Liu and Yi Li and Jihong Yu",

year = "2012",

month = jul,

doi = "10.1002/zaac.201200093",

language = "English",

volume = "638",

pages = "1362--1364",

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T2 - A new germanate compound constructed from alternately stacked pseudo triple-sheet layers

AU - Ren, Xiaoyan

AU - Liu, Jiancong

AU - Li, Yi

AU - Yu, Jihong

PY - 2012/7

Y1 - 2012/7

N2 - A novel layered germanate compound, |(C 6N 4H 21) 2|[Ge 7O 14F 6] (JU-86, JU = Jilin University), was solvothermally synthesized. Its structure consists of 4.6-net sheets built up from dissymmetric 8 3 building units. Different from those found in several metal phosphate compounds, half of the 4.6-net sheets in JU-86 are constructed from right-handed 8 3 building units and the other half are constructed from left-handed ones. Right-handed and left-handed 4.6-net sheets are stacked alternately in JU-86. Each 4.6-net sheet is sandwiched by two layers of protonated tris(2-aminoethyl)amine (tren) molecules to form an unusual pseudo triple-sheet layer through hydrogen-bonding interactions. No hydrogen bonds are found between different pseudo triple-sheet layers.

AB - A novel layered germanate compound, |(C 6N 4H 21) 2|[Ge 7O 14F 6] (JU-86, JU = Jilin University), was solvothermally synthesized. Its structure consists of 4.6-net sheets built up from dissymmetric 8 3 building units. Different from those found in several metal phosphate compounds, half of the 4.6-net sheets in JU-86 are constructed from right-handed 8 3 building units and the other half are constructed from left-handed ones. Right-handed and left-handed 4.6-net sheets are stacked alternately in JU-86. Each 4.6-net sheet is sandwiched by two layers of protonated tris(2-aminoethyl)amine (tren) molecules to form an unusual pseudo triple-sheet layer through hydrogen-bonding interactions. No hydrogen bonds are found between different pseudo triple-sheet layers.

KW - Germanates

KW - Handedness

KW - Hydrogen bonds

KW - Layered compounds

KW - Solid-state structures

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JF - Zeitschrift fur Anorganische und Allgemeine Chemie

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ER -

|(C ₆N ₄H ₂₁) ₂|[Ge ₇O ₁₄F ₆]: A new germanate compound constructed from alternately stacked pseudo triple-sheet layers

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Keywords

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