TY - JOUR
T1 - Building Better Full Manganese-Based Cathode Materials for Next-Generation Lithium-Ion Batteries
AU - Song, Jin
AU - Wang, Hangchao
AU - Zuo, Yuxuan
AU - Zhang, Kun
AU - Yang, Tonghuan
AU - Yang, Yali
AU - Gao, Chuan
AU - Chen, Tao
AU - Feng, Guang
AU - Jiang, Zewen
AU - Xiao, Wukun
AU - Luo, Tie
AU - Xia, Dingguo
N1 - Publisher Copyright:
© 2023, The Author(s).
PY - 2023/12
Y1 - 2023/12
N2 - Lithium-manganese-oxides have been exploited as promising cathode materials for many years due to their environmental friendliness, resource abundance and low biotoxicity. Nevertheless, inevitable problems, such as Jahn-Teller distortion, manganese dissolution and phase transition, still frustrate researchers; thus, progress in full manganese-based cathode materials (FMCMs) has been relatively slow and limited in recent decades. Recently, with the fast growth of vehicle electrification and large-scale energy-storage grids, there has been an urgent demand to develop novel FMCMs again; actually, new waves of research based on FMCMs are being created. Herein, we systematically review the history of FMCMs, correctly describe their structures, evaluate the advantages and challenges, and discuss the resolution strategies and latest developments. Additionally, beyond FMCMs, a profound discussion of current controversial issues, such as oxygen redox reaction, voltage decay and voltage hysteresis in Li2MnO3-based cathode materials, is also presented. This review summarizes the effectively optimized approaches and offers a few new possible enhancement methods from the perspective of the electronic-coordination-crystal structure for building better FMCMs for next-generation lithium-ion batteries. Graphical Abstract: [Figure not available: see fulltext.].
AB - Lithium-manganese-oxides have been exploited as promising cathode materials for many years due to their environmental friendliness, resource abundance and low biotoxicity. Nevertheless, inevitable problems, such as Jahn-Teller distortion, manganese dissolution and phase transition, still frustrate researchers; thus, progress in full manganese-based cathode materials (FMCMs) has been relatively slow and limited in recent decades. Recently, with the fast growth of vehicle electrification and large-scale energy-storage grids, there has been an urgent demand to develop novel FMCMs again; actually, new waves of research based on FMCMs are being created. Herein, we systematically review the history of FMCMs, correctly describe their structures, evaluate the advantages and challenges, and discuss the resolution strategies and latest developments. Additionally, beyond FMCMs, a profound discussion of current controversial issues, such as oxygen redox reaction, voltage decay and voltage hysteresis in Li2MnO3-based cathode materials, is also presented. This review summarizes the effectively optimized approaches and offers a few new possible enhancement methods from the perspective of the electronic-coordination-crystal structure for building better FMCMs for next-generation lithium-ion batteries. Graphical Abstract: [Figure not available: see fulltext.].
KW - Cathode materials
KW - Energy storage
KW - Lithium-ion batteries
KW - Manganese oxides
UR - http://www.scopus.com/inward/record.url?scp=85161378767&partnerID=8YFLogxK
U2 - 10.1007/s41918-023-00184-8
DO - 10.1007/s41918-023-00184-8
M3 - Review article
AN - SCOPUS:85161378767
SN - 2520-8489
VL - 6
JO - Electrochemical Energy Reviews
JF - Electrochemical Energy Reviews
IS - 1
M1 - 20
ER -