Bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids with high density and energy capacity as hypergolic fuels

Xingye Li; Chenbin Wang; Haibo Li; Fude Nie; Hongquan Yin; Fu Xue Chen

doi:10.1039/c7ta03241b

Bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids with high density and energy capacity as hypergolic fuels

Xingye Li, Chenbin Wang, Haibo Li, Fude Nie, Hongquan Yin, Fu Xue Chen^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

A new family of bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids were synthesized by a straightforward N-hydroboration of tetrazole followed by an ionic metathesis. The BTB-based ionic liquids are hypergolic with oxidizers and show superior energy capacity with high positive HOF (often ≥2.0 kJ g^-1), high density (≥1.2 g cm^-3), high density impulse (often ≥367 s g cm^-3) and short ignition delay times (<20 ms).

Original language	English
Pages (from-to)	15525-15528
Number of pages	4
Journal	Journal of Materials Chemistry A
Volume	5
Issue number	30
DOIs	https://doi.org/10.1039/c7ta03241b
Publication status	Published - 2017

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title = "Bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids with high density and energy capacity as hypergolic fuels",

abstract = "A new family of bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids were synthesized by a straightforward N-hydroboration of tetrazole followed by an ionic metathesis. The BTB-based ionic liquids are hypergolic with oxidizers and show superior energy capacity with high positive HOF (often ≥2.0 kJ g-1), high density (≥1.2 g cm-3), high density impulse (often ≥367 s g cm-3) and short ignition delay times (<20 ms).",

author = "Xingye Li and Chenbin Wang and Haibo Li and Fude Nie and Hongquan Yin and Chen, {Fu Xue}",

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T1 - Bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids with high density and energy capacity as hypergolic fuels

AU - Li, Xingye

AU - Wang, Chenbin

AU - Li, Haibo

AU - Nie, Fude

AU - Yin, Hongquan

AU - Chen, Fu Xue

PY - 2017

Y1 - 2017

N2 - A new family of bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids were synthesized by a straightforward N-hydroboration of tetrazole followed by an ionic metathesis. The BTB-based ionic liquids are hypergolic with oxidizers and show superior energy capacity with high positive HOF (often ≥2.0 kJ g-1), high density (≥1.2 g cm-3), high density impulse (often ≥367 s g cm-3) and short ignition delay times (<20 ms).

AB - A new family of bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids were synthesized by a straightforward N-hydroboration of tetrazole followed by an ionic metathesis. The BTB-based ionic liquids are hypergolic with oxidizers and show superior energy capacity with high positive HOF (often ≥2.0 kJ g-1), high density (≥1.2 g cm-3), high density impulse (often ≥367 s g cm-3) and short ignition delay times (<20 ms).

UR - http://www.scopus.com/inward/record.url?scp=85026807610&partnerID=8YFLogxK

U2 - 10.1039/c7ta03241b

DO - 10.1039/c7ta03241b

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VL - 5

SP - 15525

EP - 15528

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 30

ER -

Bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids with high density and energy capacity as hypergolic fuels

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