Bimetallic FeCo−N−C Catalyst for Efficient Oxygen Reduction Reaction

Meng Zhou; Zhijun Zhu; Yuan Ju; Yanling Zhai; Lei Jiao; Minmin Liu; Wenxiu Yang; Jianguo Tang

doi:10.1002/elan.202200009

Bimetallic FeCo−N−C Catalyst for Efficient Oxygen Reduction Reaction

Meng Zhou, Zhijun Zhu^*, Yuan Ju, Yanling Zhai^*, Lei Jiao, Minmin Liu, Wenxiu Yang, Jianguo Tang^*

^*Corresponding author for this work

Advanced Research Institute of Multidisciplinary Science

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Oxygen reduction reaction (ORR) is being deeply studied because of its significance in energy storage and conversion. It is an urgent and challenging task to explore low-cost ORR catalysts with excellent activity and outstanding long-term stability. Herein, we report an efficient bimetallic FeCo catalyst based on nitrogen-doped carbon (FeCo−NC) for ORR by pyrolysis of FeCo-1,10-phenanthroline complexes (FeCo-phen) supported on ZIF-8. The as-synthesized FeCo−NC catalyst shows excellent ORR activity, improved durability and excellent methanol cross poisoning resistance, which are ascribed to the formation of metal-N−C active sites, the synergistic effect between Fe and Co, as well as the porous structure.

Original language	English
Pages (from-to)	1572-1578
Number of pages	7
Journal	Electroanalysis
Volume	34
Issue number	10
DOIs	https://doi.org/10.1002/elan.202200009
Publication status	Published - Oct 2022

Keywords

bimetallic
carbon
electrocatalysis
oxygen reduction reaction

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10.1002/elan.202200009

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Zhou, M., Zhu, Z., Ju, Y., Zhai, Y., Jiao, L., Liu, M., Yang, W., & Tang, J. (2022). Bimetallic FeCo−N−C Catalyst for Efficient Oxygen Reduction Reaction. Electroanalysis, 34(10), 1572-1578. https://doi.org/10.1002/elan.202200009

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abstract = "Oxygen reduction reaction (ORR) is being deeply studied because of its significance in energy storage and conversion. It is an urgent and challenging task to explore low-cost ORR catalysts with excellent activity and outstanding long-term stability. Herein, we report an efficient bimetallic FeCo catalyst based on nitrogen-doped carbon (FeCo−NC) for ORR by pyrolysis of FeCo-1,10-phenanthroline complexes (FeCo-phen) supported on ZIF-8. The as-synthesized FeCo−NC catalyst shows excellent ORR activity, improved durability and excellent methanol cross poisoning resistance, which are ascribed to the formation of metal-N−C active sites, the synergistic effect between Fe and Co, as well as the porous structure.",

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author = "Meng Zhou and Zhijun Zhu and Yuan Ju and Yanling Zhai and Lei Jiao and Minmin Liu and Wenxiu Yang and Jianguo Tang",

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AU - Zhou, Meng

AU - Zhu, Zhijun

AU - Ju, Yuan

AU - Zhai, Yanling

AU - Jiao, Lei

AU - Liu, Minmin

AU - Yang, Wenxiu

AU - Tang, Jianguo

PY - 2022/10

Y1 - 2022/10

N2 - Oxygen reduction reaction (ORR) is being deeply studied because of its significance in energy storage and conversion. It is an urgent and challenging task to explore low-cost ORR catalysts with excellent activity and outstanding long-term stability. Herein, we report an efficient bimetallic FeCo catalyst based on nitrogen-doped carbon (FeCo−NC) for ORR by pyrolysis of FeCo-1,10-phenanthroline complexes (FeCo-phen) supported on ZIF-8. The as-synthesized FeCo−NC catalyst shows excellent ORR activity, improved durability and excellent methanol cross poisoning resistance, which are ascribed to the formation of metal-N−C active sites, the synergistic effect between Fe and Co, as well as the porous structure.

AB - Oxygen reduction reaction (ORR) is being deeply studied because of its significance in energy storage and conversion. It is an urgent and challenging task to explore low-cost ORR catalysts with excellent activity and outstanding long-term stability. Herein, we report an efficient bimetallic FeCo catalyst based on nitrogen-doped carbon (FeCo−NC) for ORR by pyrolysis of FeCo-1,10-phenanthroline complexes (FeCo-phen) supported on ZIF-8. The as-synthesized FeCo−NC catalyst shows excellent ORR activity, improved durability and excellent methanol cross poisoning resistance, which are ascribed to the formation of metal-N−C active sites, the synergistic effect between Fe and Co, as well as the porous structure.

KW - bimetallic

KW - carbon

KW - electrocatalysis

KW - oxygen reduction reaction

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JF - Electroanalysis

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ER -

Bimetallic FeCo−N−C Catalyst for Efficient Oxygen Reduction Reaction

Abstract

Keywords

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