Assembly of luminescent Ag(I) coordination architectures adjusted by modification of pyrimidine-based thioether ligands

Lei Han; Benlai Wu; Yanqing Xu; Mingyan Wu; Yaqiong Gong; Benyong Lou; Baiquan Chen; Maochun Hong

doi:10.1016/j.ica.2004.12.023

Assembly of luminescent Ag(I) coordination architectures adjusted by modification of pyrimidine-based thioether ligands

Lei Han, Benlai Wu, Yanqing Xu, Mingyan Wu, Yaqiong Gong, Benyong Lou, Baiquan Chen, Maochun Hong^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Two new structurally related pyrimidine-based thioether ligands, angular ditopic ligand 1,3-bis(2-pyrimidinylthiomethyl)benzene (L²) and linear ditopic ligand 1,4-bis(2-pyrimidinylthiomethyl)benzene (L³), have been designed and prepared. Reaction of two shaped-specific ligands with different silver(I) salts affords three novel luminescent coordination architectures: discrete metallomacrocycle [Ag₄(L²) ₂(NO₃)₄] • 2MeOH (3), 1D chain {[Ag ₂L³(NO₃)₂] • 2CCl ₃}_n (4) and 2D wire netlike structure {[AgL ³(DMF)]ClO₄ • 0.25H₂O}_n (5). The results show that the nature of organic ligands, geometric requirement of metal atoms and counter anions have great influence on the structures of metal-organic frameworks.

Original language	English
Pages (from-to)	2005-2013
Number of pages	9
Journal	Inorganica Chimica Acta
Volume	358
Issue number	6
DOIs	https://doi.org/10.1016/j.ica.2004.12.023
Publication status	Published - 30 Mar 2005
Externally published	Yes

Keywords

Coordination architecture
Ligand modification
Self-assembly
Silver complexes
Thioether ligands

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10.1016/j.ica.2004.12.023

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@article{3a60aca60dbe459f807db7e5303fd10d,

title = "Assembly of luminescent Ag(I) coordination architectures adjusted by modification of pyrimidine-based thioether ligands",

abstract = "Two new structurally related pyrimidine-based thioether ligands, angular ditopic ligand 1,3-bis(2-pyrimidinylthiomethyl)benzene (L2) and linear ditopic ligand 1,4-bis(2-pyrimidinylthiomethyl)benzene (L3), have been designed and prepared. Reaction of two shaped-specific ligands with different silver(I) salts affords three novel luminescent coordination architectures: discrete metallomacrocycle [Ag4(L2) 2(NO3)4] • 2MeOH (3), 1D chain {[Ag 2L3(NO3)2] • 2CCl 3}n (4) and 2D wire netlike structure {[AgL 3(DMF)]ClO4 • 0.25H2O}n (5). The results show that the nature of organic ligands, geometric requirement of metal atoms and counter anions have great influence on the structures of metal-organic frameworks.",

keywords = "Coordination architecture, Ligand modification, Self-assembly, Silver complexes, Thioether ligands",

author = "Lei Han and Benlai Wu and Yanqing Xu and Mingyan Wu and Yaqiong Gong and Benyong Lou and Baiquan Chen and Maochun Hong",

year = "2005",

month = mar,

day = "30",

doi = "10.1016/j.ica.2004.12.023",

language = "English",

volume = "358",

pages = "2005--2013",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "6",

}

TY - JOUR

T1 - Assembly of luminescent Ag(I) coordination architectures adjusted by modification of pyrimidine-based thioether ligands

AU - Han, Lei

AU - Wu, Benlai

AU - Xu, Yanqing

AU - Wu, Mingyan

AU - Gong, Yaqiong

AU - Lou, Benyong

AU - Chen, Baiquan

AU - Hong, Maochun

PY - 2005/3/30

Y1 - 2005/3/30

N2 - Two new structurally related pyrimidine-based thioether ligands, angular ditopic ligand 1,3-bis(2-pyrimidinylthiomethyl)benzene (L2) and linear ditopic ligand 1,4-bis(2-pyrimidinylthiomethyl)benzene (L3), have been designed and prepared. Reaction of two shaped-specific ligands with different silver(I) salts affords three novel luminescent coordination architectures: discrete metallomacrocycle [Ag4(L2) 2(NO3)4] • 2MeOH (3), 1D chain {[Ag 2L3(NO3)2] • 2CCl 3}n (4) and 2D wire netlike structure {[AgL 3(DMF)]ClO4 • 0.25H2O}n (5). The results show that the nature of organic ligands, geometric requirement of metal atoms and counter anions have great influence on the structures of metal-organic frameworks.

AB - Two new structurally related pyrimidine-based thioether ligands, angular ditopic ligand 1,3-bis(2-pyrimidinylthiomethyl)benzene (L2) and linear ditopic ligand 1,4-bis(2-pyrimidinylthiomethyl)benzene (L3), have been designed and prepared. Reaction of two shaped-specific ligands with different silver(I) salts affords three novel luminescent coordination architectures: discrete metallomacrocycle [Ag4(L2) 2(NO3)4] • 2MeOH (3), 1D chain {[Ag 2L3(NO3)2] • 2CCl 3}n (4) and 2D wire netlike structure {[AgL 3(DMF)]ClO4 • 0.25H2O}n (5). The results show that the nature of organic ligands, geometric requirement of metal atoms and counter anions have great influence on the structures of metal-organic frameworks.

KW - Coordination architecture

KW - Ligand modification

KW - Self-assembly

KW - Silver complexes

KW - Thioether ligands

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U2 - 10.1016/j.ica.2004.12.023

DO - 10.1016/j.ica.2004.12.023

M3 - Article

AN - SCOPUS:14844316034

SN - 0020-1693

VL - 358

SP - 2005

EP - 2013

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 6

ER -

Assembly of luminescent Ag(I) coordination architectures adjusted by modification of pyrimidine-based thioether ligands

Abstract

Keywords

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