Assembly of helical hydrogen bonds in a new layered aluminophosphate [C6N3H17][Al2(HPO 4)(PO4)2]

Mei Wang; Ji Yang Li; Ji Hong Yu; Qin He Pan; Xiao Wei Song; Ru Ren Xu

doi:10.1021/ic050124i

Assembly of helical hydrogen bonds in a new layered aluminophosphate [C₆N₃H₁₇][Al₂(HPO ₄)(PO₄)₂]

Mei Wang, Ji Yang Li, Ji Hong Yu, Qin He Pan, Xiao Wei Song, Ru Ren Xu^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

A new layered aluminophosphate, [C₆N₃H ₁₇][Al₂(HPO₄)(PO₄)₂] (denoted AIPO-CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the template. Its inorganic layer containing a series of bridged six-membered rings (MRs) is a new type of 4.6-net sheet built up from AlO₄, PO₂(OH)(=O), and PO ₃(=O) tetrahedra. Interestingly, inorganic helical chains of right- or left-handedness are presented in the aluminophosphate layers, and fascinating hydrogen-bonded helices are self-assembled under solvothermal conditions between organic templates and inorganic sheets via strong hydrogen bondings of O⋯N atoms. Crystal data: monoclinic, P2₁ (No. 4), a = 10.069(2) Å, b = 8.0875(16) Å, c = 10.598(2) Å, β = 94.71(3)°, z = 2, R₁ = 0.0325 [I > 2Σ(I)], and wR ₂ = 0.0807 (all data); Flack parameter: 0.03.

Original language	English
Pages (from-to)	4604-4607
Number of pages	4
Journal	Inorganic Chemistry
Volume	44
Issue number	13
DOIs	https://doi.org/10.1021/ic050124i
Publication status	Published - 27 Jun 2005
Externally published	Yes

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@article{c84c764f517e41e995f90121bf582766,

title = "Assembly of helical hydrogen bonds in a new layered aluminophosphate [C6N3H17][Al2(HPO 4)(PO4)2]",

abstract = "A new layered aluminophosphate, [C6N3H 17][Al2(HPO4)(PO4)2] (denoted AIPO-CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the template. Its inorganic layer containing a series of bridged six-membered rings (MRs) is a new type of 4.6-net sheet built up from AlO4, PO2(OH)(=O), and PO 3(=O) tetrahedra. Interestingly, inorganic helical chains of right- or left-handedness are presented in the aluminophosphate layers, and fascinating hydrogen-bonded helices are self-assembled under solvothermal conditions between organic templates and inorganic sheets via strong hydrogen bondings of O⋯N atoms. Crystal data: monoclinic, P21 (No. 4), a = 10.069(2) {\AA}, b = 8.0875(16) {\AA}, c = 10.598(2) {\AA}, β = 94.71(3)°, z = 2, R1 = 0.0325 [I > 2Σ(I)], and wR 2 = 0.0807 (all data); Flack parameter: 0.03.",

author = "Mei Wang and Li, {Ji Yang} and Yu, {Ji Hong} and Pan, {Qin He} and Song, {Xiao Wei} and Xu, {Ru Ren}",

year = "2005",

month = jun,

day = "27",

doi = "10.1021/ic050124i",

language = "English",

volume = "44",

pages = "4604--4607",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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T1 - Assembly of helical hydrogen bonds in a new layered aluminophosphate [C6N3H17][Al2(HPO 4)(PO4)2]

AU - Wang, Mei

AU - Li, Ji Yang

AU - Yu, Ji Hong

AU - Pan, Qin He

AU - Song, Xiao Wei

AU - Xu, Ru Ren

PY - 2005/6/27

Y1 - 2005/6/27

N2 - A new layered aluminophosphate, [C6N3H 17][Al2(HPO4)(PO4)2] (denoted AIPO-CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the template. Its inorganic layer containing a series of bridged six-membered rings (MRs) is a new type of 4.6-net sheet built up from AlO4, PO2(OH)(=O), and PO 3(=O) tetrahedra. Interestingly, inorganic helical chains of right- or left-handedness are presented in the aluminophosphate layers, and fascinating hydrogen-bonded helices are self-assembled under solvothermal conditions between organic templates and inorganic sheets via strong hydrogen bondings of O⋯N atoms. Crystal data: monoclinic, P21 (No. 4), a = 10.069(2) Å, b = 8.0875(16) Å, c = 10.598(2) Å, β = 94.71(3)°, z = 2, R1 = 0.0325 [I > 2Σ(I)], and wR 2 = 0.0807 (all data); Flack parameter: 0.03.

AB - A new layered aluminophosphate, [C6N3H 17][Al2(HPO4)(PO4)2] (denoted AIPO-CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the template. Its inorganic layer containing a series of bridged six-membered rings (MRs) is a new type of 4.6-net sheet built up from AlO4, PO2(OH)(=O), and PO 3(=O) tetrahedra. Interestingly, inorganic helical chains of right- or left-handedness are presented in the aluminophosphate layers, and fascinating hydrogen-bonded helices are self-assembled under solvothermal conditions between organic templates and inorganic sheets via strong hydrogen bondings of O⋯N atoms. Crystal data: monoclinic, P21 (No. 4), a = 10.069(2) Å, b = 8.0875(16) Å, c = 10.598(2) Å, β = 94.71(3)°, z = 2, R1 = 0.0325 [I > 2Σ(I)], and wR 2 = 0.0807 (all data); Flack parameter: 0.03.

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Assembly of helical hydrogen bonds in a new layered aluminophosphate [C₆N₃H₁₇][Al₂(HPO ₄)(PO₄)₂]

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