Assembly of a microporous metal-organic framework [Zn(bpdc)(DMSO)] (bpdc = 4,4′-biphenyldicarboxylate) based on paddle-wheel units affording guest inclusion

Jun Tao; Xin Yin; Rongbin Huang; Lansun Zheng; Seik Weng Ng

doi:10.1016/S1387-7003(02)00623-8

Assembly of a microporous metal-organic framework [Zn(bpdc)(DMSO)] (bpdc = 4,4′-biphenyldicarboxylate) based on paddle-wheel units affording guest inclusion

Jun Tao^*, Xin Yin, Rongbin Huang, Lansun Zheng, Seik Weng Ng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A novel metal-organic framework [Zn(bpdc)(DMSO)]·2 DMSO (1) (bpdc = 4,4′-biphenyldicarboxylate) was prepared by slow vapor diffusion method and characterized by single-crystal x-ray diffraction analysis. In the crystal structure of 1, the square grids [Zn(bpdc)(DMSO)] constructed with paddle-wheel [Zn₂(OOC)₄] building units and bpdc linkers stack over each other in a ABAB fashion to generate one-dimensional microporous channel that guest DMSO molecules occupy.

Original language	English
Pages (from-to)	975-977
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	5
Issue number	11
DOIs	https://doi.org/10.1016/S1387-7003(02)00623-8
Publication status	Published - 1 Nov 2002
Externally published	Yes

Keywords

Crystal structure
Guest inclusion
Metal-organic framework
Paddle-wheel unit

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10.1016/S1387-7003(02)00623-8

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title = "Assembly of a microporous metal-organic framework [Zn(bpdc)(DMSO)] (bpdc = 4,4′-biphenyldicarboxylate) based on paddle-wheel units affording guest inclusion",

abstract = "A novel metal-organic framework [Zn(bpdc)(DMSO)]·2 DMSO (1) (bpdc = 4,4′-biphenyldicarboxylate) was prepared by slow vapor diffusion method and characterized by single-crystal x-ray diffraction analysis. In the crystal structure of 1, the square grids [Zn(bpdc)(DMSO)] constructed with paddle-wheel [Zn2(OOC)4] building units and bpdc linkers stack over each other in a ABAB fashion to generate one-dimensional microporous channel that guest DMSO molecules occupy.",

keywords = "Crystal structure, Guest inclusion, Metal-organic framework, Paddle-wheel unit",

author = "Jun Tao and Xin Yin and Rongbin Huang and Lansun Zheng and {Weng Ng}, Seik",

year = "2002",

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doi = "10.1016/S1387-7003(02)00623-8",

language = "English",

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journal = "Inorganic Chemistry Communications",

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T1 - Assembly of a microporous metal-organic framework [Zn(bpdc)(DMSO)] (bpdc = 4,4′-biphenyldicarboxylate) based on paddle-wheel units affording guest inclusion

AU - Tao, Jun

AU - Yin, Xin

AU - Huang, Rongbin

AU - Zheng, Lansun

AU - Weng Ng, Seik

PY - 2002/11/1

Y1 - 2002/11/1

N2 - A novel metal-organic framework [Zn(bpdc)(DMSO)]·2 DMSO (1) (bpdc = 4,4′-biphenyldicarboxylate) was prepared by slow vapor diffusion method and characterized by single-crystal x-ray diffraction analysis. In the crystal structure of 1, the square grids [Zn(bpdc)(DMSO)] constructed with paddle-wheel [Zn2(OOC)4] building units and bpdc linkers stack over each other in a ABAB fashion to generate one-dimensional microporous channel that guest DMSO molecules occupy.

AB - A novel metal-organic framework [Zn(bpdc)(DMSO)]·2 DMSO (1) (bpdc = 4,4′-biphenyldicarboxylate) was prepared by slow vapor diffusion method and characterized by single-crystal x-ray diffraction analysis. In the crystal structure of 1, the square grids [Zn(bpdc)(DMSO)] constructed with paddle-wheel [Zn2(OOC)4] building units and bpdc linkers stack over each other in a ABAB fashion to generate one-dimensional microporous channel that guest DMSO molecules occupy.

KW - Crystal structure

KW - Guest inclusion

KW - Metal-organic framework

KW - Paddle-wheel unit

UR - http://www.scopus.com/inward/record.url?scp=0036829757&partnerID=8YFLogxK

U2 - 10.1016/S1387-7003(02)00623-8

DO - 10.1016/S1387-7003(02)00623-8

M3 - Article

AN - SCOPUS:0036829757

SN - 1387-7003

VL - 5

SP - 975

EP - 977

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -

Assembly of a microporous metal-organic framework [Zn(bpdc)(DMSO)] (bpdc = 4,4′-biphenyldicarboxylate) based on paddle-wheel units affording guest inclusion

Abstract

Keywords

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