Abstract
We herein describe the synthesis of two axially chiral systems (HBN and BBN) by the incorporation of B centers into binaphthyl derivatives (HPy and BPy). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.
Original language | English |
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Pages (from-to) | 15315-15319 |
Number of pages | 5 |
Journal | Inorganic Chemistry |
Volume | 61 |
Issue number | 39 |
DOIs | |
Publication status | Published - 3 Oct 2022 |