Anion-effect on hydrogen generation from sodium borohydride solution

Ying Bai; Feng Wu; Chuan Wu; Li Ying Bao; Bao Lian Yi; Hua Min Zhang

Anion-effect on hydrogen generation from sodium borohydride solution

Ying Bai^*, Feng Wu, Chuan Wu, Li Ying Bao, Bao Lian Yi, Hua Min Zhang

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The anion effect of Cl^- and NO₃^- on hydrogen generation from sodium borohydride solution was studied. It is found that there are two competitive reactions, which produce metal borides and metal hydroxides, respectively. Cl^- can help produce metal borides in the solution, which generates high activities to accelerate the following hydrolytic reaction. While NO₃^- can induce the producing of metal hydroxides, which has no catalytic activities and will suppress the hydrogen generation reaction.

Original language	English
Pages (from-to)	40-42
Number of pages	3
Journal	Xiandai Huagong/Modern Chemical Industry
Volume	26
Issue number	10
Publication status	Published - Oct 2006

Keywords

Anion effect
Fuel cell
Hydrogen generation
Sodium borohydride

Cite this

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title = "Anion-effect on hydrogen generation from sodium borohydride solution",

abstract = "The anion effect of Cl- and NO3- on hydrogen generation from sodium borohydride solution was studied. It is found that there are two competitive reactions, which produce metal borides and metal hydroxides, respectively. Cl- can help produce metal borides in the solution, which generates high activities to accelerate the following hydrolytic reaction. While NO3- can induce the producing of metal hydroxides, which has no catalytic activities and will suppress the hydrogen generation reaction.",

keywords = "Anion effect, Fuel cell, Hydrogen generation, Sodium borohydride",

author = "Ying Bai and Feng Wu and Chuan Wu and Bao, {Li Ying} and Yi, {Bao Lian} and Zhang, {Hua Min}",

year = "2006",

month = oct,

language = "English",

volume = "26",

pages = "40--42",

journal = "Xiandai Huagong/Modern Chemical Industry",

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T1 - Anion-effect on hydrogen generation from sodium borohydride solution

AU - Bai, Ying

AU - Wu, Feng

AU - Wu, Chuan

AU - Bao, Li Ying

AU - Yi, Bao Lian

AU - Zhang, Hua Min

PY - 2006/10

Y1 - 2006/10

N2 - The anion effect of Cl- and NO3- on hydrogen generation from sodium borohydride solution was studied. It is found that there are two competitive reactions, which produce metal borides and metal hydroxides, respectively. Cl- can help produce metal borides in the solution, which generates high activities to accelerate the following hydrolytic reaction. While NO3- can induce the producing of metal hydroxides, which has no catalytic activities and will suppress the hydrogen generation reaction.

AB - The anion effect of Cl- and NO3- on hydrogen generation from sodium borohydride solution was studied. It is found that there are two competitive reactions, which produce metal borides and metal hydroxides, respectively. Cl- can help produce metal borides in the solution, which generates high activities to accelerate the following hydrolytic reaction. While NO3- can induce the producing of metal hydroxides, which has no catalytic activities and will suppress the hydrogen generation reaction.

KW - Anion effect

KW - Fuel cell

KW - Hydrogen generation

KW - Sodium borohydride

UR - http://www.scopus.com/inward/record.url?scp=33845906674&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33845906674

SN - 0253-4320

VL - 26

SP - 40

EP - 42

JO - Xiandai Huagong/Modern Chemical Industry

JF - Xiandai Huagong/Modern Chemical Industry

IS - 10

ER -

Anion-effect on hydrogen generation from sodium borohydride solution

Abstract

Keywords

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