An unexpected photoelectronic effect from [Co(en)3] 2(Zr2F12)(SiF6)·4H 2O, a compound ontaining an H-bonded assembly of discrete [Co(en)3]3+, (Zr2F12)4-, and (SiF6)2- ions

Yu Du; Min Yang; Jihong Yu; Qinhe Pan; Ruren Xu

doi:10.1002/anie.200502514

An unexpected photoelectronic effect from [Co(en)₃] ₂(Zr₂F₁₂)(SiF₆)·4H ₂O, a compound ontaining an H-bonded assembly of discrete [Co(en)₃]³⁺, (Zr₂F₁₂)^4-, and (SiF₆)^2- ions

Yu Du^*, Min Yang, Jihong Yu, Qinhe Pan, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

(Graph Presented) Hydrogen-bonded network: A hydrothermal synthesis delivers the titled compound, which consists of an H-bonded network of discrete [Co(en)₃]³⁺, (Zr₂F₁₂)^4-, and (SiF₆)^2- ions. It exhibits an unexpected photoelectronic effect in the near-UV region (see figure).

Original language	English
Pages (from-to)	7988-7990
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	48
DOIs	https://doi.org/10.1002/anie.200502514
Publication status	Published - 9 Dec 2005
Externally published	Yes

Keywords

Cobalt
Hydrogen bonds
Hydrothermal synthesis
Materials science
Photoelectronic effect

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10.1002/anie.200502514

Cite this

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title = "An unexpected photoelectronic effect from [Co(en)3] 2(Zr2F12)(SiF6)·4H 2O, a compound ontaining an H-bonded assembly of discrete [Co(en)3]3+, (Zr2F12)4-, and (SiF6)2- ions",

abstract = "(Graph Presented) Hydrogen-bonded network: A hydrothermal synthesis delivers the titled compound, which consists of an H-bonded network of discrete [Co(en)3]3+, (Zr2F12)4-, and (SiF6)2- ions. It exhibits an unexpected photoelectronic effect in the near-UV region (see figure).",

keywords = "Cobalt, Hydrogen bonds, Hydrothermal synthesis, Materials science, Photoelectronic effect",

author = "Yu Du and Min Yang and Jihong Yu and Qinhe Pan and Ruren Xu",

year = "2005",

month = dec,

day = "9",

doi = "10.1002/anie.200502514",

language = "English",

volume = "44",

pages = "7988--7990",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "48",

}

An unexpected photoelectronic effect from [Co(en)₃] ₂(Zr₂F₁₂)(SiF₆)·4H ₂O, a compound ontaining an H-bonded assembly of discrete [Co(en)₃]³⁺, (Zr₂F₁₂)^4-, and (SiF₆)^2- ions. / Du, Yu; Yang, Min; Yu, Jihong et al.
In: Angewandte Chemie - International Edition, Vol. 44, No. 48, 09.12.2005, p. 7988-7990.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - An unexpected photoelectronic effect from [Co(en)3] 2(Zr2F12)(SiF6)·4H 2O, a compound ontaining an H-bonded assembly of discrete [Co(en)3]3+, (Zr2F12)4-, and (SiF6)2- ions

AU - Du, Yu

AU - Yang, Min

AU - Yu, Jihong

AU - Pan, Qinhe

AU - Xu, Ruren

PY - 2005/12/9

Y1 - 2005/12/9

N2 - (Graph Presented) Hydrogen-bonded network: A hydrothermal synthesis delivers the titled compound, which consists of an H-bonded network of discrete [Co(en)3]3+, (Zr2F12)4-, and (SiF6)2- ions. It exhibits an unexpected photoelectronic effect in the near-UV region (see figure).

AB - (Graph Presented) Hydrogen-bonded network: A hydrothermal synthesis delivers the titled compound, which consists of an H-bonded network of discrete [Co(en)3]3+, (Zr2F12)4-, and (SiF6)2- ions. It exhibits an unexpected photoelectronic effect in the near-UV region (see figure).

KW - Cobalt

KW - Hydrogen bonds

KW - Hydrothermal synthesis

KW - Materials science

KW - Photoelectronic effect

UR - http://www.scopus.com/inward/record.url?scp=29144504505&partnerID=8YFLogxK

U2 - 10.1002/anie.200502514

DO - 10.1002/anie.200502514

M3 - Article

AN - SCOPUS:29144504505

SN - 1433-7851

VL - 44

SP - 7988

EP - 7990

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 48

ER -

An unexpected photoelectronic effect from [Co(en)₃] ₂(Zr₂F₁₂)(SiF₆)·4H ₂O, a compound ontaining an H-bonded assembly of discrete [Co(en)₃]³⁺, (Zr₂F₁₂)^4-, and (SiF₆)^2- ions

Abstract

Keywords

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