An inorganic-organic hybrid compound built from polyoxovanadate cluster and Mn (II) complexes

Lei Wang; Yi Li; Yanyan Wang; Zhiqiang Liang; Jihong Yu; Ruren Xu

doi:10.1016/j.inoche.2011.06.028

An inorganic-organic hybrid compound built from polyoxovanadate cluster and Mn (II) complexes

Lei Wang, Yi Li, Yanyan Wang, Zhiqiang Liang^*, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A novel inorganic-organic hybrid compound [Mn(teta)][Mn(teta)(H ₂O)₂]₂{V₁₈O₄₂(Cl)} •8H₂O (1) (teta: triethylenetetramine) has been hydrothermally synthesized and characterized by TGA, IR and XPS analysis. Its structure is determined by single-crystal X-ray diffraction analysis. Compound 1 exhibits a rare 2-D planar square lattice (sql net), which was constructed by the well known {V₁₈O₄₂} cluster as node and two distinct Mn (II) complexes, [Mn(teta)] and [Mn(teta)(H₂O)₂], as single/double μ₂-bridging linkers. This type sql net with two distinct Mn (II) complexes is the first example found in polyoxovanadates. The magnetic study shows that there exists antiferromagnetic interaction within 1.

Original language	English
Pages (from-to)	1640-1643
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2011.06.028
Publication status	Published - Oct 2011
Externally published	Yes

Keywords

Hydrothermal synthesis
Inorganic-organic hybrid material
Magnetic properties
Polyoxovanadates

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10.1016/j.inoche.2011.06.028

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title = "An inorganic-organic hybrid compound built from polyoxovanadate cluster and Mn (II) complexes",

abstract = "A novel inorganic-organic hybrid compound [Mn(teta)][Mn(teta)(H 2O)2]2{V18O42(Cl)} •8H2O (1) (teta: triethylenetetramine) has been hydrothermally synthesized and characterized by TGA, IR and XPS analysis. Its structure is determined by single-crystal X-ray diffraction analysis. Compound 1 exhibits a rare 2-D planar square lattice (sql net), which was constructed by the well known {V18O42} cluster as node and two distinct Mn (II) complexes, [Mn(teta)] and [Mn(teta)(H2O)2], as single/double μ2-bridging linkers. This type sql net with two distinct Mn (II) complexes is the first example found in polyoxovanadates. The magnetic study shows that there exists antiferromagnetic interaction within 1.",

keywords = "Hydrothermal synthesis, Inorganic-organic hybrid material, Magnetic properties, Polyoxovanadates",

author = "Lei Wang and Yi Li and Yanyan Wang and Zhiqiang Liang and Jihong Yu and Ruren Xu",

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journal = "Inorganic Chemistry Communications",

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T1 - An inorganic-organic hybrid compound built from polyoxovanadate cluster and Mn (II) complexes

AU - Wang, Lei

AU - Li, Yi

AU - Wang, Yanyan

AU - Liang, Zhiqiang

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2011/10

Y1 - 2011/10

N2 - A novel inorganic-organic hybrid compound [Mn(teta)][Mn(teta)(H 2O)2]2{V18O42(Cl)} •8H2O (1) (teta: triethylenetetramine) has been hydrothermally synthesized and characterized by TGA, IR and XPS analysis. Its structure is determined by single-crystal X-ray diffraction analysis. Compound 1 exhibits a rare 2-D planar square lattice (sql net), which was constructed by the well known {V18O42} cluster as node and two distinct Mn (II) complexes, [Mn(teta)] and [Mn(teta)(H2O)2], as single/double μ2-bridging linkers. This type sql net with two distinct Mn (II) complexes is the first example found in polyoxovanadates. The magnetic study shows that there exists antiferromagnetic interaction within 1.

AB - A novel inorganic-organic hybrid compound [Mn(teta)][Mn(teta)(H 2O)2]2{V18O42(Cl)} •8H2O (1) (teta: triethylenetetramine) has been hydrothermally synthesized and characterized by TGA, IR and XPS analysis. Its structure is determined by single-crystal X-ray diffraction analysis. Compound 1 exhibits a rare 2-D planar square lattice (sql net), which was constructed by the well known {V18O42} cluster as node and two distinct Mn (II) complexes, [Mn(teta)] and [Mn(teta)(H2O)2], as single/double μ2-bridging linkers. This type sql net with two distinct Mn (II) complexes is the first example found in polyoxovanadates. The magnetic study shows that there exists antiferromagnetic interaction within 1.

KW - Hydrothermal synthesis

KW - Inorganic-organic hybrid material

KW - Magnetic properties

KW - Polyoxovanadates

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DO - 10.1016/j.inoche.2011.06.028

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SN - 1387-7003

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SP - 1640

EP - 1643

JO - Inorganic Chemistry Communications

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ER -

An inorganic-organic hybrid compound built from polyoxovanadate cluster and Mn (II) complexes

Abstract

Keywords

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