Amide as nitrogen source: Amination and mechanism

Juan Xu; Jiarong Li; Zhen Wei; Qi Zhang; Daxin Shi

doi:10.6023/cjoc201305053

Amide as nitrogen source: Amination and mechanism

Juan Xu, Jiarong Li, Zhen Wei, Qi Zhang, Daxin Shi^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The mechanism of C-N bond formation with amide as nitrogen source was disclosed. The process included the cleavage of amide C-N bond to form amine and then to construct new C-N bond. With the cooperation of Lewis acid, aryl halides, aryl triflates, boronic acids, aryl siloxanes and azoles could be aminated by amide as nitrogen source.

Original language	English
Pages (from-to)	2435-2439
Number of pages	5
Journal	Chinese Journal of Organic Chemistry
Volume	33
Issue number	11
DOIs	https://doi.org/10.6023/cjoc201305053
Publication status	Published - Nov 2013

Keywords

Amide
Cleavage and formation of C-N bond
Lewis acid complex of amine
Nitrogen source

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title = "Amide as nitrogen source: Amination and mechanism",

abstract = "The mechanism of C-N bond formation with amide as nitrogen source was disclosed. The process included the cleavage of amide C-N bond to form amine and then to construct new C-N bond. With the cooperation of Lewis acid, aryl halides, aryl triflates, boronic acids, aryl siloxanes and azoles could be aminated by amide as nitrogen source.",

keywords = "Amide, Cleavage and formation of C-N bond, Lewis acid complex of amine, Nitrogen source",

author = "Juan Xu and Jiarong Li and Zhen Wei and Qi Zhang and Daxin Shi",

year = "2013",

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T2 - Amination and mechanism

AU - Xu, Juan

AU - Li, Jiarong

AU - Wei, Zhen

AU - Zhang, Qi

AU - Shi, Daxin

PY - 2013/11

Y1 - 2013/11

N2 - The mechanism of C-N bond formation with amide as nitrogen source was disclosed. The process included the cleavage of amide C-N bond to form amine and then to construct new C-N bond. With the cooperation of Lewis acid, aryl halides, aryl triflates, boronic acids, aryl siloxanes and azoles could be aminated by amide as nitrogen source.

AB - The mechanism of C-N bond formation with amide as nitrogen source was disclosed. The process included the cleavage of amide C-N bond to form amine and then to construct new C-N bond. With the cooperation of Lewis acid, aryl halides, aryl triflates, boronic acids, aryl siloxanes and azoles could be aminated by amide as nitrogen source.

KW - Amide

KW - Cleavage and formation of C-N bond

KW - Lewis acid complex of amine

KW - Nitrogen source

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U2 - 10.6023/cjoc201305053

DO - 10.6023/cjoc201305053

M3 - Article

AN - SCOPUS:84891440392

SN - 0253-2786

VL - 33

SP - 2435

EP - 2439

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 11

ER -

Amide as nitrogen source: Amination and mechanism

Abstract

Keywords

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