Abstract
The first anionic aluminophosphate molecular sieve [Al12P13O52]3-[(CH2)6N4H3]3+, denoted AlPO-CJB1, which possesses Bronsted acidity upon removing the templates, is reported. The framework is constructed from strict alternation of Alcentered polyhedra (AlO4 and AlO5) and P-centered PO4 tetrahedra by sharing oxygen atoms at vertices, which creates the anionic open-framework in contrast to previous AlPO(4-n) with neutral open-frameworks.
Original language | English |
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Pages (from-to) | 2517-2519 |
Number of pages | 3 |
Journal | Chemistry of Materials |
Volume | 12 |
Issue number | 9 |
DOIs | |
Publication status | Published - 2000 |
Externally published | Yes |