Abstract
Zinc-air batteries will be a promising candidate for storage energy and power supply due to their high specific energy, environmental compatibility, and economic availability. However, the problem of cycle life of rechargeable zinc-air battery remains unresolved mainly because of dendrite growth of electrodeposited zinc and performance degradation of air electrode. Here we show that rechargeable zinc-air battery with an optimized structure can stably run at large current densities, where air electrode is connected to the charging electrode through a stainless steel frame, and the effective area of charging electrode is larger than that of zinc electrode by way of a trapezoidal structure. This battery structure can control morphological change of zinc electrode and monitor dendrite growth without increasing the battery volume. The results demonstrate that the charge-discharge efficiency of rechargeable zinc-air battery can be improved by nickel foam as gas diffusion layer of air electrode, calcium oxide additive to the electrolyte, or a permanent magnet in parallel with the electrode. The lifetime of rechargeable zinc-air battery can be extended by electrolyte flow or battery structure optimization. These findings will be available for other metal-air batteries and electrolytic metal industry.
Original language | English |
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Pages (from-to) | 848-856 |
Number of pages | 9 |
Journal | Applied Energy |
Volume | 225 |
DOIs | |
Publication status | Published - 1 Sept 2018 |
Keywords
- Cycle life
- Dendrite growth
- Electrolyte management
- Magnetic field
- Rechargeable zinc-air battery
- Structure optimization