Advanced rechargeable zinc-air battery with parameter optimization

Keliang Wang*, Pucheng Pei, Yichun Wang, Cheng Liao, Wei Wang, Shangwei Huang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

81 Citations (Scopus)

Abstract

Zinc-air batteries will be a promising candidate for storage energy and power supply due to their high specific energy, environmental compatibility, and economic availability. However, the problem of cycle life of rechargeable zinc-air battery remains unresolved mainly because of dendrite growth of electrodeposited zinc and performance degradation of air electrode. Here we show that rechargeable zinc-air battery with an optimized structure can stably run at large current densities, where air electrode is connected to the charging electrode through a stainless steel frame, and the effective area of charging electrode is larger than that of zinc electrode by way of a trapezoidal structure. This battery structure can control morphological change of zinc electrode and monitor dendrite growth without increasing the battery volume. The results demonstrate that the charge-discharge efficiency of rechargeable zinc-air battery can be improved by nickel foam as gas diffusion layer of air electrode, calcium oxide additive to the electrolyte, or a permanent magnet in parallel with the electrode. The lifetime of rechargeable zinc-air battery can be extended by electrolyte flow or battery structure optimization. These findings will be available for other metal-air batteries and electrolytic metal industry.

Original languageEnglish
Pages (from-to)848-856
Number of pages9
JournalApplied Energy
Volume225
DOIs
Publication statusPublished - 1 Sept 2018

Keywords

  • Cycle life
  • Dendrite growth
  • Electrolyte management
  • Magnetic field
  • Rechargeable zinc-air battery
  • Structure optimization

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