Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-butyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

Ming Lan Ge; Li Sheng Wang; Mi Yi Li; Jun Sheng Wu

doi:10.1021/je700282w

Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-butyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

Ming Lan Ge, Li Sheng Wang^*, Mi Yi Li, Jun Sheng Wu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

71 Citations (Scopus)

Abstract

Activity coefficients at infinite dilution γy_i ^∞ have been measured for 17 organic solutes-alkanes, alkenes, and alkyl benzenes-in the ionic liquid 1-buty 1-3-methylimidazolium trifluoromethanesulfonate ([BMIM][CF₃SO₃]) by the gas-liquid chromatographic method with the ionic liquid as the stationary phase. The measurements were carried out from (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution H_i^E,∞ of the solutes in the ionic liquid were also derived from the temperature dependence of the γ_i^∞ values.

Original language	English
Pages (from-to)	2257-2260
Number of pages	4
Journal	Journal of Chemical and Engineering Data
Volume	52
Issue number	6
DOIs	https://doi.org/10.1021/je700282w
Publication status	Published - Nov 2007

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@article{79afed3801f44a8382e4618af6e93884,

title = "Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-butyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography",

abstract = "Activity coefficients at infinite dilution γyi ∞ have been measured for 17 organic solutes-alkanes, alkenes, and alkyl benzenes-in the ionic liquid 1-buty 1-3-methylimidazolium trifluoromethanesulfonate ([BMIM][CF3SO3]) by the gas-liquid chromatographic method with the ionic liquid as the stationary phase. The measurements were carried out from (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution HiE,∞ of the solutes in the ionic liquid were also derived from the temperature dependence of the γi∞ values.",

author = "Ge, {Ming Lan} and Wang, {Li Sheng} and Li, {Mi Yi} and Wu, {Jun Sheng}",

year = "2007",

month = nov,

doi = "10.1021/je700282w",

language = "English",

volume = "52",

pages = "2257--2260",

journal = "Journal of Chemical and Engineering Data",

issn = "0021-9568",

publisher = "American Chemical Society",

number = "6",

}

Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-butyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography. / Ge, Ming Lan; Wang, Li Sheng; Li, Mi Yi et al.
In: Journal of Chemical and Engineering Data, Vol. 52, No. 6, 11.2007, p. 2257-2260.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-butyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

AU - Ge, Ming Lan

AU - Wang, Li Sheng

AU - Li, Mi Yi

AU - Wu, Jun Sheng

PY - 2007/11

Y1 - 2007/11

N2 - Activity coefficients at infinite dilution γyi ∞ have been measured for 17 organic solutes-alkanes, alkenes, and alkyl benzenes-in the ionic liquid 1-buty 1-3-methylimidazolium trifluoromethanesulfonate ([BMIM][CF3SO3]) by the gas-liquid chromatographic method with the ionic liquid as the stationary phase. The measurements were carried out from (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution HiE,∞ of the solutes in the ionic liquid were also derived from the temperature dependence of the γi∞ values.

AB - Activity coefficients at infinite dilution γyi ∞ have been measured for 17 organic solutes-alkanes, alkenes, and alkyl benzenes-in the ionic liquid 1-buty 1-3-methylimidazolium trifluoromethanesulfonate ([BMIM][CF3SO3]) by the gas-liquid chromatographic method with the ionic liquid as the stationary phase. The measurements were carried out from (303.15 to 363.15) K. The partial molar excess enthalpies at infinite dilution HiE,∞ of the solutes in the ionic liquid were also derived from the temperature dependence of the γi∞ values.

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SN - 0021-9568

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SP - 2257

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JO - Journal of Chemical and Engineering Data

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IS - 6

ER -

Activity coefficients at infinite dilution of alkanes, alkenes, and alkyl benzenes in 1-butyl-3-methylimidazolium trifluoromethanesulfonate using gas-liquid chromatography

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