Achiral phenolic N-oxides as additives: An alternative strategy for asymmetric cyanosilylation of ketones

Bin He; Fu Xue Chen; Yan Li; Xiaoming Feng; Guolin Zhang

doi:10.1016/j.tetlet.2004.05.069

Achiral phenolic N-oxides as additives: An alternative strategy for asymmetric cyanosilylation of ketones

Bin He, Fu Xue Chen, Yan Li, Xiaoming Feng^*, Guolin Zhang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

The activation of chiral titanium(IV) complexes with additives, phenolic N-oxides, is found to provide an alternative strategy for asymmetric cyanosilylation of ketones in excellent yield with up to 82% ee.

Original language	English
Pages (from-to)	5465-5467
Number of pages	3
Journal	Tetrahedron Letters
Volume	45
Issue number	28
DOIs	https://doi.org/10.1016/j.tetlet.2004.05.069
Publication status	Published - 5 Jul 2004
Externally published	Yes

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10.1016/j.tetlet.2004.05.069

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@article{ced7477982e3438fae5ecc6487ec214d,

title = "Achiral phenolic N-oxides as additives: An alternative strategy for asymmetric cyanosilylation of ketones",

abstract = "The activation of chiral titanium(IV) complexes with additives, phenolic N-oxides, is found to provide an alternative strategy for asymmetric cyanosilylation of ketones in excellent yield with up to 82% ee.",

author = "Bin He and Chen, {Fu Xue} and Yan Li and Xiaoming Feng and Guolin Zhang",

year = "2004",

month = jul,

day = "5",

doi = "10.1016/j.tetlet.2004.05.069",

language = "English",

volume = "45",

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journal = "Tetrahedron Letters",

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T1 - Achiral phenolic N-oxides as additives

T2 - An alternative strategy for asymmetric cyanosilylation of ketones

AU - He, Bin

AU - Chen, Fu Xue

AU - Li, Yan

AU - Feng, Xiaoming

AU - Zhang, Guolin

PY - 2004/7/5

Y1 - 2004/7/5

N2 - The activation of chiral titanium(IV) complexes with additives, phenolic N-oxides, is found to provide an alternative strategy for asymmetric cyanosilylation of ketones in excellent yield with up to 82% ee.

AB - The activation of chiral titanium(IV) complexes with additives, phenolic N-oxides, is found to provide an alternative strategy for asymmetric cyanosilylation of ketones in excellent yield with up to 82% ee.

UR - http://www.scopus.com/inward/record.url?scp=2942635053&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2004.05.069

DO - 10.1016/j.tetlet.2004.05.069

M3 - Article

AN - SCOPUS:2942635053

SN - 0040-4039

VL - 45

SP - 5465

EP - 5467

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 28

ER -

Achiral phenolic N-oxides as additives: An alternative strategy for asymmetric cyanosilylation of ketones

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