A three-dimensional complex with a one-dimensional cobalt-hydroxyl chain based on planar nonanuclear clusters showing spin-canted antiferromagnetism

Bao Li; Zhao Li; Rong Jia Wei; Fan Yu; Xi Chen; Yun Peng Xie; Tian Le Zhang; Jun Tao

doi:10.1021/ic503041b

A three-dimensional complex with a one-dimensional cobalt-hydroxyl chain based on planar nonanuclear clusters showing spin-canted antiferromagnetism

Bao Li^*, Zhao Li, Rong Jia Wei, Fan Yu, Xi Chen, Yun Peng Xie, Tian Le Zhang, Jun Tao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

A new three-dimensional magnetic network, [Co₉(OH)₆(C₄₂H₂₄O₁₈P₃N₃)₂(H₂O)₈] (1), has been successfully prepared by utilizing the flexible hexacarboxylate ligand derived from cyclotriphosphazene, which had been characterized by single-crystal X-ray diffraction and magnetic measurement. This compound consists of one-dimensional (1D) cobalt-hydroxyl chains based on planar nonanuclear clusters, which are located in the b-c plane to form the nearly two-dimensional cobalt layer. Magnetic measurements reveal that 1 shows spin-canted antiferromagnetism with spin-glass behavior. These results suggest that reasonable design and choice of large carboxylate ligand based on a specific scaffold could be effective for the construction of magnetic materials based on a novel 1D magnetic chain.

Original language	English
Pages (from-to)	3331-3336
Number of pages	6
Journal	Inorganic Chemistry
Volume	54
Issue number	7
DOIs	https://doi.org/10.1021/ic503041b
Publication status	Published - 6 Apr 2015
Externally published	Yes

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title = "A three-dimensional complex with a one-dimensional cobalt-hydroxyl chain based on planar nonanuclear clusters showing spin-canted antiferromagnetism",

abstract = "A new three-dimensional magnetic network, [Co9(OH)6(C42H24O18P3N3)2(H2O)8] (1), has been successfully prepared by utilizing the flexible hexacarboxylate ligand derived from cyclotriphosphazene, which had been characterized by single-crystal X-ray diffraction and magnetic measurement. This compound consists of one-dimensional (1D) cobalt-hydroxyl chains based on planar nonanuclear clusters, which are located in the b-c plane to form the nearly two-dimensional cobalt layer. Magnetic measurements reveal that 1 shows spin-canted antiferromagnetism with spin-glass behavior. These results suggest that reasonable design and choice of large carboxylate ligand based on a specific scaffold could be effective for the construction of magnetic materials based on a novel 1D magnetic chain.",

author = "Bao Li and Zhao Li and Wei, {Rong Jia} and Fan Yu and Xi Chen and Xie, {Yun Peng} and Zhang, {Tian Le} and Jun Tao",

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T1 - A three-dimensional complex with a one-dimensional cobalt-hydroxyl chain based on planar nonanuclear clusters showing spin-canted antiferromagnetism

AU - Li, Bao

AU - Li, Zhao

AU - Wei, Rong Jia

AU - Yu, Fan

AU - Chen, Xi

AU - Xie, Yun Peng

AU - Zhang, Tian Le

AU - Tao, Jun

PY - 2015/4/6

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AB - A new three-dimensional magnetic network, [Co9(OH)6(C42H24O18P3N3)2(H2O)8] (1), has been successfully prepared by utilizing the flexible hexacarboxylate ligand derived from cyclotriphosphazene, which had been characterized by single-crystal X-ray diffraction and magnetic measurement. This compound consists of one-dimensional (1D) cobalt-hydroxyl chains based on planar nonanuclear clusters, which are located in the b-c plane to form the nearly two-dimensional cobalt layer. Magnetic measurements reveal that 1 shows spin-canted antiferromagnetism with spin-glass behavior. These results suggest that reasonable design and choice of large carboxylate ligand based on a specific scaffold could be effective for the construction of magnetic materials based on a novel 1D magnetic chain.

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A three-dimensional complex with a one-dimensional cobalt-hydroxyl chain based on planar nonanuclear clusters showing spin-canted antiferromagnetism

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