A supramolecular approach for the synthesis of cross-linked ionic polyacetylene network gels

Yong Tian; Lingwei Kong; Huiling Mao; Jianbing Shi; Bin Tong; Zhengxu Cai; Yuping Dong

doi:10.1039/c9qm00577c

A supramolecular approach for the synthesis of cross-linked ionic polyacetylene network gels

Yong Tian, Lingwei Kong, Huiling Mao, Jianbing Shi, Bin Tong, Zhengxu Cai^*, Yuping Dong

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The poly((para-(4-methylpiperazin-1-yl)methanone)phenylacetylene) (PPA) polymer with a 66% trans-cisoid configuration was used to prepare a π-conjugated ionic polyacetylene network gel (π-IPN gel) by a simple cross-linking reaction between PPA and suberic acid in an appropriate functional group ratio. The PPA hydrogel could be synthesized in bulk quantities with a uniform morphology of self-assembled interconnected nanospheres. In addition, experimental results revealed that the PPA-based π-IPN gel led to an enhanced electrical storage ability and demonstrated immense potential for use in flexible solid-state energy storage devices.

Original language	English
Pages (from-to)	645-650
Number of pages	6
Journal	Materials Chemistry Frontiers
Volume	4
Issue number	2
DOIs	https://doi.org/10.1039/c9qm00577c
Publication status	Published - Feb 2020

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abstract = "The poly((para-(4-methylpiperazin-1-yl)methanone)phenylacetylene) (PPA) polymer with a 66% trans-cisoid configuration was used to prepare a π-conjugated ionic polyacetylene network gel (π-IPN gel) by a simple cross-linking reaction between PPA and suberic acid in an appropriate functional group ratio. The PPA hydrogel could be synthesized in bulk quantities with a uniform morphology of self-assembled interconnected nanospheres. In addition, experimental results revealed that the PPA-based π-IPN gel led to an enhanced electrical storage ability and demonstrated immense potential for use in flexible solid-state energy storage devices.",

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AU - Mao, Huiling

AU - Shi, Jianbing

AU - Tong, Bin

AU - Cai, Zhengxu

AU - Dong, Yuping

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AB - The poly((para-(4-methylpiperazin-1-yl)methanone)phenylacetylene) (PPA) polymer with a 66% trans-cisoid configuration was used to prepare a π-conjugated ionic polyacetylene network gel (π-IPN gel) by a simple cross-linking reaction between PPA and suberic acid in an appropriate functional group ratio. The PPA hydrogel could be synthesized in bulk quantities with a uniform morphology of self-assembled interconnected nanospheres. In addition, experimental results revealed that the PPA-based π-IPN gel led to an enhanced electrical storage ability and demonstrated immense potential for use in flexible solid-state energy storage devices.

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A supramolecular approach for the synthesis of cross-linked ionic polyacetylene network gels

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