A squaraine-linked mesoporous covalent organic framework

Atsushi Nagai; Xiong Chen; Xiao Feng; Xuesong Ding; Zhaoqi Guo; Donglin Jiang

doi:10.1002/anie.201300256

A squaraine-linked mesoporous covalent organic framework

Atsushi Nagai, Xiong Chen, Xiao Feng, Xuesong Ding, Zhaoqi Guo, Donglin Jiang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

310 Citations (Scopus)

Abstract

π in the sky: A squaraine-linked, conjugated two-dimensional porphyrin covalent organic framework (COF; see scheme; C: gray, H: white, N: blue, Cu: red) was synthesized. Owing to the π-conjugated linkage together with the eclipsed stacking of the units, this COF exhibits enhanced chemical and thermal stabilities. It absorbs a broad range of light, from the ultraviolet to the visible, and near-infrared regions, and shows potential as a photocatalyst.

Original language	English
Pages (from-to)	3770-3774
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	13
DOIs	https://doi.org/10.1002/anie.201300256
Publication status	Published - 25 Mar 2013
Externally published	Yes

Keywords

conjugation
covalent organic frameworks
photocatalyst
porphyrinoids
synthetic methods

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10.1002/anie.201300256

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abstract = "π in the sky: A squaraine-linked, conjugated two-dimensional porphyrin covalent organic framework (COF; see scheme; C: gray, H: white, N: blue, Cu: red) was synthesized. Owing to the π-conjugated linkage together with the eclipsed stacking of the units, this COF exhibits enhanced chemical and thermal stabilities. It absorbs a broad range of light, from the ultraviolet to the visible, and near-infrared regions, and shows potential as a photocatalyst.",

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AU - Nagai, Atsushi

AU - Chen, Xiong

AU - Feng, Xiao

AU - Ding, Xuesong

AU - Guo, Zhaoqi

AU - Jiang, Donglin

PY - 2013/3/25

Y1 - 2013/3/25

N2 - π in the sky: A squaraine-linked, conjugated two-dimensional porphyrin covalent organic framework (COF; see scheme; C: gray, H: white, N: blue, Cu: red) was synthesized. Owing to the π-conjugated linkage together with the eclipsed stacking of the units, this COF exhibits enhanced chemical and thermal stabilities. It absorbs a broad range of light, from the ultraviolet to the visible, and near-infrared regions, and shows potential as a photocatalyst.

AB - π in the sky: A squaraine-linked, conjugated two-dimensional porphyrin covalent organic framework (COF; see scheme; C: gray, H: white, N: blue, Cu: red) was synthesized. Owing to the π-conjugated linkage together with the eclipsed stacking of the units, this COF exhibits enhanced chemical and thermal stabilities. It absorbs a broad range of light, from the ultraviolet to the visible, and near-infrared regions, and shows potential as a photocatalyst.

KW - conjugation

KW - covalent organic frameworks

KW - photocatalyst

KW - porphyrinoids

KW - synthetic methods

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A squaraine-linked mesoporous covalent organic framework

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Keywords

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