Abstract
π in the sky: A squaraine-linked, conjugated two-dimensional porphyrin covalent organic framework (COF; see scheme; C: gray, H: white, N: blue, Cu: red) was synthesized. Owing to the π-conjugated linkage together with the eclipsed stacking of the units, this COF exhibits enhanced chemical and thermal stabilities. It absorbs a broad range of light, from the ultraviolet to the visible, and near-infrared regions, and shows potential as a photocatalyst.
Original language | English |
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Pages (from-to) | 3770-3774 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 52 |
Issue number | 13 |
DOIs | |
Publication status | Published - 25 Mar 2013 |
Externally published | Yes |
Keywords
- conjugation
- covalent organic frameworks
- photocatalyst
- porphyrinoids
- synthetic methods