A series of coordination polymers based on a V-shaped multicarboxylate and bisimidazole ligands: Synthesis, characterization and luminescent properties

Huadong Guo; Yongnian Yan; Xianmin Guo; Nan Wang; Yanjuan Qi

doi:10.1016/j.molstruc.2015.11.031

A series of coordination polymers based on a V-shaped multicarboxylate and bisimidazole ligands: Synthesis, characterization and luminescent properties

Huadong Guo, Yongnian Yan, Xianmin Guo^*, Nan Wang, Yanjuan Qi

^*Corresponding author for this work

Changchun Normal University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Based on a V-shaped multicarboxylic acid and various bisimidazole ligands, six new coordination polymers, namely, [Zn₄(otba) (1,4-bix)₄]·3H₂O (1), [Ni₄(otba)₂(1,4-bix)₃(H₂O)₂]·2H₂O (2), [Zn₂(H₂otba)₂(bib) (H₂O)₂] (3), [Cd₂(H₂otba)₂(bib)]·2H₂O (4), [Zn₃(otba)₂(bidpe)₂(H₂O)₂] (5), [Ni₂(H₂otba)₂(bidpe)₃(H₂O)₂]·H₂O (6) (H₄otba = 3,5,3′,5′-oxytetrabenzoic acid, 1,4-bix = 1,2-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazol-1-yl)benzene and bidpe = 4,4'-bis(imidazol-1-yl)diphenyl ether) have been hydrothermally synthesized and structurally characterized. Compound 1 displays an uncommon hexanodal 3D 4-connected network. Compound 2 features a trinodal 3D (4, 4, 6)-connected framework. Compound 3 shows an interesting polythreaded 1D→3D species. Compound 4 exhibits a binodal 3D (3, 8)-connected network. Compound 5 displays a three-fold interpenetration of trinodal (3, 3, 4)-connected network. Compound 6 shows a five-fold interpenetration of five-connected bilayer network. The luminescent properties of compounds 1, 3, 4 and 5 were also measured.

Original language	English
Pages (from-to)	134-143
Number of pages	10
Journal	Journal of Molecular Structure
Volume	1108
DOIs	https://doi.org/10.1016/j.molstruc.2015.11.031
Publication status	Published - 15 Mar 2016
Externally published	Yes

Keywords

Bisimidazole ligand
Coordination polymers
Multicarboxylic acid
Topology

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10.1016/j.molstruc.2015.11.031

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@article{28ba8746672846519bef7d8ba20d9e63,

title = "A series of coordination polymers based on a V-shaped multicarboxylate and bisimidazole ligands: Synthesis, characterization and luminescent properties",

abstract = "Based on a V-shaped multicarboxylic acid and various bisimidazole ligands, six new coordination polymers, namely, [Zn4(otba) (1,4-bix)4]·3H2O (1), [Ni4(otba)2(1,4-bix)3(H2O)2]·2H2O (2), [Zn2(H2otba)2(bib) (H2O)2] (3), [Cd2(H2otba)2(bib)]·2H2O (4), [Zn3(otba)2(bidpe)2(H2O)2] (5), [Ni2(H2otba)2(bidpe)3(H2O)2]·H2O (6) (H4otba = 3,5,3′,5′-oxytetrabenzoic acid, 1,4-bix = 1,2-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazol-1-yl)benzene and bidpe = 4,4'-bis(imidazol-1-yl)diphenyl ether) have been hydrothermally synthesized and structurally characterized. Compound 1 displays an uncommon hexanodal 3D 4-connected network. Compound 2 features a trinodal 3D (4, 4, 6)-connected framework. Compound 3 shows an interesting polythreaded 1D→3D species. Compound 4 exhibits a binodal 3D (3, 8)-connected network. Compound 5 displays a three-fold interpenetration of trinodal (3, 3, 4)-connected network. Compound 6 shows a five-fold interpenetration of five-connected bilayer network. The luminescent properties of compounds 1, 3, 4 and 5 were also measured.",

keywords = "Bisimidazole ligand, Coordination polymers, Multicarboxylic acid, Topology",

author = "Huadong Guo and Yongnian Yan and Xianmin Guo and Nan Wang and Yanjuan Qi",

year = "2016",

month = mar,

day = "15",

doi = "10.1016/j.molstruc.2015.11.031",

language = "English",

volume = "1108",

pages = "134--143",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - A series of coordination polymers based on a V-shaped multicarboxylate and bisimidazole ligands

T2 - Synthesis, characterization and luminescent properties

AU - Guo, Huadong

AU - Yan, Yongnian

AU - Guo, Xianmin

AU - Wang, Nan

AU - Qi, Yanjuan

PY - 2016/3/15

Y1 - 2016/3/15

N2 - Based on a V-shaped multicarboxylic acid and various bisimidazole ligands, six new coordination polymers, namely, [Zn4(otba) (1,4-bix)4]·3H2O (1), [Ni4(otba)2(1,4-bix)3(H2O)2]·2H2O (2), [Zn2(H2otba)2(bib) (H2O)2] (3), [Cd2(H2otba)2(bib)]·2H2O (4), [Zn3(otba)2(bidpe)2(H2O)2] (5), [Ni2(H2otba)2(bidpe)3(H2O)2]·H2O (6) (H4otba = 3,5,3′,5′-oxytetrabenzoic acid, 1,4-bix = 1,2-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazol-1-yl)benzene and bidpe = 4,4'-bis(imidazol-1-yl)diphenyl ether) have been hydrothermally synthesized and structurally characterized. Compound 1 displays an uncommon hexanodal 3D 4-connected network. Compound 2 features a trinodal 3D (4, 4, 6)-connected framework. Compound 3 shows an interesting polythreaded 1D→3D species. Compound 4 exhibits a binodal 3D (3, 8)-connected network. Compound 5 displays a three-fold interpenetration of trinodal (3, 3, 4)-connected network. Compound 6 shows a five-fold interpenetration of five-connected bilayer network. The luminescent properties of compounds 1, 3, 4 and 5 were also measured.

AB - Based on a V-shaped multicarboxylic acid and various bisimidazole ligands, six new coordination polymers, namely, [Zn4(otba) (1,4-bix)4]·3H2O (1), [Ni4(otba)2(1,4-bix)3(H2O)2]·2H2O (2), [Zn2(H2otba)2(bib) (H2O)2] (3), [Cd2(H2otba)2(bib)]·2H2O (4), [Zn3(otba)2(bidpe)2(H2O)2] (5), [Ni2(H2otba)2(bidpe)3(H2O)2]·H2O (6) (H4otba = 3,5,3′,5′-oxytetrabenzoic acid, 1,4-bix = 1,2-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazol-1-yl)benzene and bidpe = 4,4'-bis(imidazol-1-yl)diphenyl ether) have been hydrothermally synthesized and structurally characterized. Compound 1 displays an uncommon hexanodal 3D 4-connected network. Compound 2 features a trinodal 3D (4, 4, 6)-connected framework. Compound 3 shows an interesting polythreaded 1D→3D species. Compound 4 exhibits a binodal 3D (3, 8)-connected network. Compound 5 displays a three-fold interpenetration of trinodal (3, 3, 4)-connected network. Compound 6 shows a five-fold interpenetration of five-connected bilayer network. The luminescent properties of compounds 1, 3, 4 and 5 were also measured.

KW - Bisimidazole ligand

KW - Coordination polymers

KW - Multicarboxylic acid

KW - Topology

UR - http://www.scopus.com/inward/record.url?scp=84954556214&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2015.11.031

DO - 10.1016/j.molstruc.2015.11.031

M3 - Article

AN - SCOPUS:84954556214

SN - 0022-2860

VL - 1108

SP - 134

EP - 143

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

A series of coordination polymers based on a V-shaped multicarboxylate and bisimidazole ligands: Synthesis, characterization and luminescent properties

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Keywords

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