A novel sintering method to obtain fully dense gadolinia doped ceria by applying a direct current

Xiaoming Hao, Yajie Liu, Zhenhua Wang*, Jinshuo Qiao, Kening Sun

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

126 Citations (Scopus)

Abstract

A fully dense Ce 0.8Gd 0.2O 1.9 (gadolinia doped ceria, GDC) is obtained by a novel using a sintering technique for several seconds at 545 °C by applying a direct current (DC) electrical field of 70 V cm -1. The onset applied field value of this phenomenon is 20 V cm -1, and the volume specific power dissipation for the onset of flash sintering is about ∼10 mW mm -3. Through contrast with the shrinkage strain of the conventional sintering as well as scanning electron microscopy (SEM) analysis, we conclude that GDC specimens are sintered to fully density under various applied fields. In addition, we demonstrate that the grain size of GDC is decreasing with the increase of applied field and the decrease of sintering temperature. Through calculation, we find that sintering of GDC can be explained by the Joule heating from the applied electrical field.

Original languageEnglish
Pages (from-to)86-91
Number of pages6
JournalJournal of Power Sources
Volume210
DOIs
Publication statusPublished - 15 Jul 2012

Keywords

  • Flash Sintering
  • Gadolinia doped Ceria
  • Solid Oxide Fuel Cells

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