TY - JOUR
T1 - A novel environmental-friendly and safe unpacking powder without magnesium, aluminum and sulphur for fireworks
AU - Han, Zhiyue
AU - Jiang, Qi
AU - Du, Zhiming
AU - Huey Hoon, Hng
AU - Yu, Yue
AU - Zhang, Yupeng
AU - Li, Gong
AU - Sun, Yue
N1 - Publisher Copyright:
© 2019 Elsevier B.V.
PY - 2019/7/5
Y1 - 2019/7/5
N2 - A novel environmental-friendly unpacking powder for fireworks which has no sulfur, no magnesium, no aluminum or their alloys has been prepared in this study: potassium perchlorate (75%), potassium hydrogen terephthalate (13%), micronano porous silicon (9%), carbon (2%), ferrocene (1%). The PM2.5 and PM10 were collected by the ambient air particulate sampler, and the gas product was tested with a smoke analyzer and gas chromatograph to investigate its environmental-friendly performance. The detonation radius was measured by similar triangulation method, and p–t curves were measured in a closed bomb to investigate its practicality. The heat of combustion, sensitivity and hygroscopicity of the formula were measured according to China fireworks industry standard to verify the safety of the novel unpacking powder. The test results suggest that new unpacking powder using micronano porous silicon can effectively reduce the PM content and the product does not contain SO2, so it can be applied to export.
AB - A novel environmental-friendly unpacking powder for fireworks which has no sulfur, no magnesium, no aluminum or their alloys has been prepared in this study: potassium perchlorate (75%), potassium hydrogen terephthalate (13%), micronano porous silicon (9%), carbon (2%), ferrocene (1%). The PM2.5 and PM10 were collected by the ambient air particulate sampler, and the gas product was tested with a smoke analyzer and gas chromatograph to investigate its environmental-friendly performance. The detonation radius was measured by similar triangulation method, and p–t curves were measured in a closed bomb to investigate its practicality. The heat of combustion, sensitivity and hygroscopicity of the formula were measured according to China fireworks industry standard to verify the safety of the novel unpacking powder. The test results suggest that new unpacking powder using micronano porous silicon can effectively reduce the PM content and the product does not contain SO2, so it can be applied to export.
KW - Environmental-friendly
KW - Firework
KW - Security
KW - Unpacking powder
UR - http://www.scopus.com/inward/record.url?scp=85064451456&partnerID=8YFLogxK
U2 - 10.1016/j.jhazmat.2019.04.001
DO - 10.1016/j.jhazmat.2019.04.001
M3 - Article
C2 - 31005019
AN - SCOPUS:85064451456
SN - 0304-3894
VL - 373
SP - 835
EP - 843
JO - Journal of Hazardous Materials
JF - Journal of Hazardous Materials
ER -