A new open-framework indium phosphate-phosphite containing intersecting extra-large 16-ring channels

Zhaojun Dong; Yan Yan; Yi Li; Jiyang Li; Jihong Yu; Ruren Xu

doi:10.1016/j.inoche.2011.02.019

A new open-framework indium phosphate-phosphite containing intersecting extra-large 16-ring channels

Zhaojun Dong, Yan Yan, Yi Li, Jiyang Li^*, Jihong Yu, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A new open-framework indium phosphate-phosphite [In₉(H ₂O)₆(HPO₃)₁₃(H₂PO ₃)₂(PO₄)(HPO₄)][(C₆N ₂H₁₈)₃] (InHPO-CJ1) has been hydrothermally synthesized by using 2-methyl-1,5-pentanediamine (MPMD) as the structure-directing agent. It presents a unique pillar-layer framework topology containing three-dimensional intersecting extra-large 16-ring channels. ³¹P MAS NMR has been studied to confirm the four different coordinations of P atoms in the as-synthesized compound.

Original language	English
Pages (from-to)	727-730
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	5
DOIs	https://doi.org/10.1016/j.inoche.2011.02.019
Publication status	Published - May 2011
Externally published	Yes

Keywords

Extra-large 16-ring channel
Hydrothermal synthesis
Indium phosphate-phosphite
NMR

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10.1016/j.inoche.2011.02.019

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title = "A new open-framework indium phosphate-phosphite containing intersecting extra-large 16-ring channels",

abstract = "A new open-framework indium phosphate-phosphite [In9(H 2O)6(HPO3)13(H2PO 3)2(PO4)(HPO4)][(C6N 2H18)3] (InHPO-CJ1) has been hydrothermally synthesized by using 2-methyl-1,5-pentanediamine (MPMD) as the structure-directing agent. It presents a unique pillar-layer framework topology containing three-dimensional intersecting extra-large 16-ring channels. 31P MAS NMR has been studied to confirm the four different coordinations of P atoms in the as-synthesized compound.",

keywords = "Extra-large 16-ring channel, Hydrothermal synthesis, Indium phosphate-phosphite, NMR",

author = "Zhaojun Dong and Yan Yan and Yi Li and Jiyang Li and Jihong Yu and Ruren Xu",

year = "2011",

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T1 - A new open-framework indium phosphate-phosphite containing intersecting extra-large 16-ring channels

AU - Dong, Zhaojun

AU - Yan, Yan

AU - Li, Yi

AU - Li, Jiyang

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2011/5

Y1 - 2011/5

N2 - A new open-framework indium phosphate-phosphite [In9(H 2O)6(HPO3)13(H2PO 3)2(PO4)(HPO4)][(C6N 2H18)3] (InHPO-CJ1) has been hydrothermally synthesized by using 2-methyl-1,5-pentanediamine (MPMD) as the structure-directing agent. It presents a unique pillar-layer framework topology containing three-dimensional intersecting extra-large 16-ring channels. 31P MAS NMR has been studied to confirm the four different coordinations of P atoms in the as-synthesized compound.

AB - A new open-framework indium phosphate-phosphite [In9(H 2O)6(HPO3)13(H2PO 3)2(PO4)(HPO4)][(C6N 2H18)3] (InHPO-CJ1) has been hydrothermally synthesized by using 2-methyl-1,5-pentanediamine (MPMD) as the structure-directing agent. It presents a unique pillar-layer framework topology containing three-dimensional intersecting extra-large 16-ring channels. 31P MAS NMR has been studied to confirm the four different coordinations of P atoms in the as-synthesized compound.

KW - Extra-large 16-ring channel

KW - Hydrothermal synthesis

KW - Indium phosphate-phosphite

KW - NMR

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DO - 10.1016/j.inoche.2011.02.019

M3 - Article

AN - SCOPUS:79954429482

SN - 1387-7003

VL - 14

SP - 727

EP - 730

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 5

ER -

A new open-framework indium phosphate-phosphite containing intersecting extra-large 16-ring channels

Abstract

Keywords

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