A new nickel complex-templated layered aluminophosphate [Ni(C4N3H13)(C4N3H14)H2O][Al3P4O16]

Mei Wang, Jiyang Li, Qinhe Pan, Jihong Yu, Xiaowei Song, Ruren Xu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

A new layered aluminophosphate [Ni(C4N3H13)(C4N3H14)H2O][Al3P4O16] has been prepared from a hydrothermal system Al(i-PrO)3{single bond}Ni(OAc)2{single bond}H3PO4{single bond}diethylenetriamine{single bond}H2O, and characterized by single-crystal X-ray diffraction, ICP, CHN and TG analyses. Its structure is built up from the alternation of AlO4 and PO3({double bond, long}O) tetrahedra to from 4.6.8-net sheets stacked in an ABAB sequence. The nickel complex Ni(C4N3H13)(C4N3H14)H2O that is formed under hydrothermal conditions locates in the interlayer region and interacts with the inorganic sheets through H-bonds.

Original languageEnglish
Pages (from-to)1079-1084
Number of pages6
JournalSolid State Sciences
Volume8
Issue number9
DOIs
Publication statusPublished - Sept 2006
Externally publishedYes

Keywords

  • Host-guest interactions
  • Hydrothermal synthesis
  • Layered aluminophosphate
  • Nickel complex
  • Structure

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