A new entry to cascade organocatalysis: Reactions of stable sulfur ylides and nitroolefins sequentially catalyzed by thiourea and DMAP

Liang Qiu Lu; Yi Ju Cao; Xiao Peng Liu; Jing An; Chang Jiang Yao; Zhi Hui Ming; Wen Jing Xiao

doi:10.1021/ja800746q

A new entry to cascade organocatalysis: Reactions of stable sulfur ylides and nitroolefins sequentially catalyzed by thiourea and DMAP

Liang Qiu Lu, Yi Ju Cao, Xiao Peng Liu, Jing An, Chang Jiang Yao, Zhi Hui Ming, Wen Jing Xiao^*

^*Corresponding author for this work

Central China Normal University

Research output: Contribution to journal › Article › peer-review

157 Citations (Scopus)

Abstract

A novel cascade organocatalysis that allows efficient and rapid access to diverse and structurally complex oxazolidin-2-ones from simple starting materials and catalysts has been developed. A possible mechanism of this reaction has been proposed based on D- and ¹³C-labeling experiments.

Original language	English
Pages (from-to)	6946-6948
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	130
Issue number	22
DOIs	https://doi.org/10.1021/ja800746q
Publication status	Published - 4 Jun 2008
Externally published	Yes

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10.1021/ja800746q

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title = "A new entry to cascade organocatalysis: Reactions of stable sulfur ylides and nitroolefins sequentially catalyzed by thiourea and DMAP",

abstract = "A novel cascade organocatalysis that allows efficient and rapid access to diverse and structurally complex oxazolidin-2-ones from simple starting materials and catalysts has been developed. A possible mechanism of this reaction has been proposed based on D- and 13C-labeling experiments.",

author = "Lu, {Liang Qiu} and Cao, {Yi Ju} and Liu, {Xiao Peng} and Jing An and Yao, {Chang Jiang} and Ming, {Zhi Hui} and Xiao, {Wen Jing}",

year = "2008",

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T2 - Reactions of stable sulfur ylides and nitroolefins sequentially catalyzed by thiourea and DMAP

AU - Lu, Liang Qiu

AU - Cao, Yi Ju

AU - Liu, Xiao Peng

AU - An, Jing

AU - Yao, Chang Jiang

AU - Ming, Zhi Hui

AU - Xiao, Wen Jing

PY - 2008/6/4

Y1 - 2008/6/4

N2 - A novel cascade organocatalysis that allows efficient and rapid access to diverse and structurally complex oxazolidin-2-ones from simple starting materials and catalysts has been developed. A possible mechanism of this reaction has been proposed based on D- and 13C-labeling experiments.

AB - A novel cascade organocatalysis that allows efficient and rapid access to diverse and structurally complex oxazolidin-2-ones from simple starting materials and catalysts has been developed. A possible mechanism of this reaction has been proposed based on D- and 13C-labeling experiments.

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U2 - 10.1021/ja800746q

DO - 10.1021/ja800746q

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SN - 0002-7863

VL - 130

SP - 6946

EP - 6948

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 22

ER -

A new entry to cascade organocatalysis: Reactions of stable sulfur ylides and nitroolefins sequentially catalyzed by thiourea and DMAP

Abstract

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