TY - JOUR
T1 - A New Energetic Material and its Risk Research
AU - Han, Zhiyue
AU - Zhang, Yinghao
AU - Yao, Qian
AU - Du, Zhiming
AU - He, Chunlin
AU - Zhang, Jingchang
N1 - Publisher Copyright:
Copyright © 2015 HeteroCorporation.
PY - 2016/1
Y1 - 2016/1
N2 - (Figure Presented) Bis (1, 5-diamino-4-methyl-tetrazolium) azotetrazolate (BMDATZT) was synthesized with high yield in this work. The yield is 97.46%. The structure was characterized by IR, 1H NMR, and MS. The single crystal of BMDATZT•2H2O was first cultivated. The heat of formation, detonation pressure, and detonation velocity were first calculated. The crystalline density of BMDATZT•2H2O is 1.573 g/cm3. BMDATZT has high detonation pressure and detonation velocity (P =25.06 GPa, D = 7.805 km s-1), which are higher than those of 2,4,6-Trinitrotoluene (TNT). Its thermal and mechanical sensitivities are moderate. Therefore, it is a kind of insensitive nitrogen-rich energetic ionic salt with good performance, and it has potential application prospect in gas generating agent, explosive and solid propellant.
AB - (Figure Presented) Bis (1, 5-diamino-4-methyl-tetrazolium) azotetrazolate (BMDATZT) was synthesized with high yield in this work. The yield is 97.46%. The structure was characterized by IR, 1H NMR, and MS. The single crystal of BMDATZT•2H2O was first cultivated. The heat of formation, detonation pressure, and detonation velocity were first calculated. The crystalline density of BMDATZT•2H2O is 1.573 g/cm3. BMDATZT has high detonation pressure and detonation velocity (P =25.06 GPa, D = 7.805 km s-1), which are higher than those of 2,4,6-Trinitrotoluene (TNT). Its thermal and mechanical sensitivities are moderate. Therefore, it is a kind of insensitive nitrogen-rich energetic ionic salt with good performance, and it has potential application prospect in gas generating agent, explosive and solid propellant.
UR - http://www.scopus.com/inward/record.url?scp=84970928413&partnerID=8YFLogxK
U2 - 10.1002/jhet.2488
DO - 10.1002/jhet.2488
M3 - Article
AN - SCOPUS:84970928413
SN - 0022-152X
VL - 53
SP - 325
EP - 331
JO - Journal of Heterocyclic Chemistry
JF - Journal of Heterocyclic Chemistry
IS - 1
ER -