A model on the Mn2+ luminescence band redshift with Mn(II) doping and aggregation within CdS:Mn microwires

Yong You Zhang, Rui Bin Liu*, Li Jie Shi, Bing Suo Zou, Arshad Kamran Muhammad

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

We report the microphoto-luminescence band redshifts with individual and multi-Mn(II) ion emissions within CdS microwires. The localized exciton magnetic polarons (LEMPs) corresponding to the d - d optical transitions of Mn(II) account for this shift. This LEMP emission from the double-, three- and four-Mn(II) ions with ferromagnetic coupling after photoexcitation can happen in diluted magnetic semiconductors, except for the individual Mn(II) doping. In addition, a simple spin-exchange polaronic model is established to account for these emission peaks well. Through this model, we can verify the local geometry of the Mn(II) ions in CdS microwires.

Original languageEnglish
Article number067802
JournalChinese Physics Letters
Volume31
Issue number6
DOIs
Publication statusPublished - Jun 2014

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