A metallocene with Ga-Zr bonds: Cp 2Zr(GaR) 2 (Cp = C 5H 5; R = -C 6H 3-2,6-(2,4,6-i-Pr 3C 6H 2) 2)

Xiao Juan Yang; Brandon Quillian; Yuzhong Wang; Pingrong Wei; Gregory H. Robinson

doi:10.1021/om049343m

A metallocene with Ga-Zr bonds: Cp ₂Zr(GaR) ₂ (Cp = C ₅H ₅; R = -C ₆H ₃-2,6-(2,4,6-i-Pr ₃C ₆H ₂) ₂)

Xiao Juan Yang, Brandon Quillian, Yuzhong Wang, Pingrong Wei, Gregory H. Robinson^*

^*Corresponding author for this work

University of Georgia

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The reaction of sodium metal with Cp ₂ZrCl ₂ and RGaCl ₂ in hexane affords Cp ₂Zr(GaR) ₂ (R = -C ₆H ₃-2,6-(2,4,6-i-Pr ₃C ₆H ₂) ₂) as deep green-black air-sensitive crystals. Essentially, Cp ₂Zr(GaR) ₂ is isoelectronic with the well-known 18-electron zirconocene dicarbonyl, Cp ₂-Zr(CO) ₂, complex. The title compound is the first example of an organometallic compound containing Ga-Zr bonds (Ga-Zr = 2.6350(8) Å).

Original language	English
Pages (from-to)	5119-5120
Number of pages	2
Journal	Organometallics
Volume	23
Issue number	22
DOIs	https://doi.org/10.1021/om049343m
Publication status	Published - 25 Oct 2004
Externally published	Yes

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title = "A metallocene with Ga-Zr bonds: Cp 2Zr(GaR) 2 (Cp = C 5H 5; R = -C 6H 3-2,6-(2,4,6-i-Pr 3C 6H 2) 2)",

abstract = "The reaction of sodium metal with Cp 2ZrCl 2 and RGaCl 2 in hexane affords Cp 2Zr(GaR) 2 (R = -C 6H 3-2,6-(2,4,6-i-Pr 3C 6H 2) 2) as deep green-black air-sensitive crystals. Essentially, Cp 2Zr(GaR) 2 is isoelectronic with the well-known 18-electron zirconocene dicarbonyl, Cp 2-Zr(CO) 2, complex. The title compound is the first example of an organometallic compound containing Ga-Zr bonds (Ga-Zr = 2.6350(8) {\AA}).",

author = "Yang, {Xiao Juan} and Brandon Quillian and Yuzhong Wang and Pingrong Wei and Robinson, {Gregory H.}",

year = "2004",

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doi = "10.1021/om049343m",

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TY - JOUR

T1 - A metallocene with Ga-Zr bonds

T2 - Cp 2Zr(GaR) 2 (Cp = C 5H 5; R = -C 6H 3-2,6-(2,4,6-i-Pr 3C 6H 2) 2)

AU - Yang, Xiao Juan

AU - Quillian, Brandon

AU - Wang, Yuzhong

AU - Wei, Pingrong

AU - Robinson, Gregory H.

PY - 2004/10/25

Y1 - 2004/10/25

N2 - The reaction of sodium metal with Cp 2ZrCl 2 and RGaCl 2 in hexane affords Cp 2Zr(GaR) 2 (R = -C 6H 3-2,6-(2,4,6-i-Pr 3C 6H 2) 2) as deep green-black air-sensitive crystals. Essentially, Cp 2Zr(GaR) 2 is isoelectronic with the well-known 18-electron zirconocene dicarbonyl, Cp 2-Zr(CO) 2, complex. The title compound is the first example of an organometallic compound containing Ga-Zr bonds (Ga-Zr = 2.6350(8) Å).

AB - The reaction of sodium metal with Cp 2ZrCl 2 and RGaCl 2 in hexane affords Cp 2Zr(GaR) 2 (R = -C 6H 3-2,6-(2,4,6-i-Pr 3C 6H 2) 2) as deep green-black air-sensitive crystals. Essentially, Cp 2Zr(GaR) 2 is isoelectronic with the well-known 18-electron zirconocene dicarbonyl, Cp 2-Zr(CO) 2, complex. The title compound is the first example of an organometallic compound containing Ga-Zr bonds (Ga-Zr = 2.6350(8) Å).

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U2 - 10.1021/om049343m

DO - 10.1021/om049343m

M3 - Article

AN - SCOPUS:8344256613

SN - 0276-7333

VL - 23

SP - 5119

EP - 5120

JO - Organometallics

JF - Organometallics

IS - 22

ER -

A metallocene with Ga-Zr bonds: Cp ₂Zr(GaR) ₂ (Cp = C ₅H ₅; R = -C ₆H ₃-2,6-(2,4,6-i-Pr ₃C ₆H ₂) ₂)

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