A gallogermanate zeolite with eleven-membered-ring channels

Yan Xu; Yi Li; Yide Han; Xiaowei Song; Jihong Yu

doi:10.1002/anie.201300846

A gallogermanate zeolite with eleven-membered-ring channels

Yan Xu, Yi Li, Yide Han, Xiaowei Song, Jihong Yu

Jilin University

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Ring the change: The gallogermanate zeolite |(Ni(C₃H ₁₀N₂)₃)₃₆Ni_4.7|[Ga _81.4Ge_206.6O₅₇₆], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [3¹².4³.6².11⁶] cavities, induced by chiral [Ni(1,2-PDA)₃]²⁺ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

Original language	English
Pages (from-to)	5501-5503
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	21
DOIs	https://doi.org/10.1002/anie.201300846
Publication status	Published - 17 May 2013
Externally published	Yes

Keywords

enantiomers
gallogermanates
low framework density
template synthesis
zeolite analogues

Access to Document

10.1002/anie.201300846

Cite this

Xu, Y., Li, Y., Han, Y., Song, X., & Yu, J. (2013). A gallogermanate zeolite with eleven-membered-ring channels. Angewandte Chemie - International Edition, 52(21), 5501-5503. https://doi.org/10.1002/anie.201300846

@article{e7a20605bc3b4a15adb29de9debd338b,

title = "A gallogermanate zeolite with eleven-membered-ring channels",

abstract = "Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.",

keywords = "enantiomers, gallogermanates, low framework density, template synthesis, zeolite analogues",

author = "Yan Xu and Yi Li and Yide Han and Xiaowei Song and Jihong Yu",

year = "2013",

month = may,

day = "17",

doi = "10.1002/anie.201300846",

language = "English",

volume = "52",

pages = "5501--5503",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "21",

}

TY - JOUR

T1 - A gallogermanate zeolite with eleven-membered-ring channels

AU - Xu, Yan

AU - Li, Yi

AU - Han, Yide

AU - Song, Xiaowei

AU - Yu, Jihong

PY - 2013/5/17

Y1 - 2013/5/17

N2 - Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

AB - Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

KW - enantiomers

KW - gallogermanates

KW - low framework density

KW - template synthesis

KW - zeolite analogues

UR - http://www.scopus.com/inward/record.url?scp=84877712857&partnerID=8YFLogxK

U2 - 10.1002/anie.201300846

DO - 10.1002/anie.201300846

M3 - Article

AN - SCOPUS:84877712857

SN - 1433-7851

VL - 52

SP - 5501

EP - 5503

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 21

ER -

A gallogermanate zeolite with eleven-membered-ring channels

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this