A gallogermanate zeolite with eleven-membered-ring channels

Yan Xu; Yi Li; Yide Han; Xiaowei Song; Jihong Yu

doi:10.1002/anie.201300846

A gallogermanate zeolite with eleven-membered-ring channels

Yan Xu, Yi Li, Yide Han, Xiaowei Song, Jihong Yu

Jilin University

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Ring the change: The gallogermanate zeolite |(Ni(C₃H ₁₀N₂)₃)₃₆Ni_4.7|[Ga _81.4Ge_206.6O₅₇₆], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [3¹².4³.6².11⁶] cavities, induced by chiral [Ni(1,2-PDA)₃]²⁺ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

Original language	English
Pages (from-to)	5501-5503
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	21
DOIs	https://doi.org/10.1002/anie.201300846
Publication status	Published - 17 May 2013
Externally published	Yes

Keywords

enantiomers
gallogermanates
low framework density
template synthesis
zeolite analogues

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10.1002/anie.201300846

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abstract = "Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.",

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T1 - A gallogermanate zeolite with eleven-membered-ring channels

AU - Xu, Yan

AU - Li, Yi

AU - Han, Yide

AU - Song, Xiaowei

AU - Yu, Jihong

PY - 2013/5/17

Y1 - 2013/5/17

N2 - Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

AB - Ring the change: The gallogermanate zeolite |(Ni(C3H 10N2)3)36Ni4.7|[Ga 81.4Ge206.6O576], which has three-dimensional intersecting 11-membered-ring channels (see picture, left), was synthesized. It has the lowest framework density of all known oxide zeolites and features pairs of chiral [312.43.62.116] cavities, induced by chiral [Ni(1,2-PDA)3]2+ cations formed insitu (see picture, right). 1,2-PDA=1,2-diaminopropane.

KW - enantiomers

KW - gallogermanates

KW - low framework density

KW - template synthesis

KW - zeolite analogues

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M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

A gallogermanate zeolite with eleven-membered-ring channels

Abstract

Keywords

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