Li, J., Gao, Z. R., Lin, Q. F., Liu, C., Gao, F., Lin, C., Zhang, S., Deng, H., Mayoral, A., Fan, W., Luo, S., Chen, X., He, H., Camblor, M. A., Chen, F. J., & Yu, J. (2023). A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate. Science, 379(6629), 283-287. https://doi.org/10.1126/science.ade1771
Li, Jian ; Gao, Zihao Rei ; Lin, Qing Fang et al. / A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate. In: Science. 2023 ; Vol. 379, No. 6629. pp. 283-287.
@article{1642bbd6fe9d4abd8012d191deba5fb7,
title = "A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate",
abstract = "Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.",
author = "Jian Li and Gao, {Zihao Rei} and Lin, {Qing Fang} and Chenxu Liu and Fangxin Gao and Cong Lin and Siyao Zhang and Hua Deng and Alvaro Mayoral and Wei Fan and Song Luo and Xiaobo Chen and Hong He and Camblor, {Miguel A.} and Chen, {Fei Jian} and Jihong Yu",
note = "Publisher Copyright: Copyright {\textcopyright} 2023 the authors, some rights reserved.",
year = "2023",
month = jan,
day = "20",
doi = "10.1126/science.ade1771",
language = "English",
volume = "379",
pages = "283--287",
journal = "Science",
issn = "0036-8075",
publisher = "American Association for the Advancement of Science",
number = "6629",
}
Li, J, Gao, ZR, Lin, QF, Liu, C, Gao, F, Lin, C, Zhang, S, Deng, H, Mayoral, A, Fan, W, Luo, S, Chen, X, He, H, Camblor, MA, Chen, FJ & Yu, J 2023, 'A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate', Science, vol. 379, no. 6629, pp. 283-287. https://doi.org/10.1126/science.ade1771
A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate. / Li, Jian; Gao, Zihao Rei; Lin, Qing Fang et al.
In:
Science, Vol. 379, No. 6629, 20.01.2023, p. 283-287.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate
AU - Li, Jian
AU - Gao, Zihao Rei
AU - Lin, Qing Fang
AU - Liu, Chenxu
AU - Gao, Fangxin
AU - Lin, Cong
AU - Zhang, Siyao
AU - Deng, Hua
AU - Mayoral, Alvaro
AU - Fan, Wei
AU - Luo, Song
AU - Chen, Xiaobo
AU - He, Hong
AU - Camblor, Miguel A.
AU - Chen, Fei Jian
AU - Yu, Jihong
N1 - Publisher Copyright:
Copyright © 2023 the authors, some rights reserved.
PY - 2023/1/20
Y1 - 2023/1/20
N2 - Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.
AB - Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.
UR - http://www.scopus.com/inward/record.url?scp=85146535830&partnerID=8YFLogxK
U2 - 10.1126/science.ade1771
DO - 10.1126/science.ade1771
M3 - Article
C2 - 36656929
AN - SCOPUS:85146535830
SN - 0036-8075
VL - 379
SP - 283
EP - 287
JO - Science
JF - Science
IS - 6629
ER -
Li J, Gao ZR, Lin QF, Liu C, Gao F, Lin C et al. A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate. Science. 2023 Jan 20;379(6629):283-287. doi: 10.1126/science.ade1771
