TY - JOUR
T1 - 4,5-Bis(5-tetrazolyl)-1,2,3-triazole
T2 - Synthesis and Performance
AU - Du, Zhiming
AU - Zhang, Yinghao
AU - Han, Zhiyue
AU - Yao, Qian
N1 - Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2015/12/1
Y1 - 2015/12/1
N2 - 4,5-Bis(5-tetrazolyl)-1,2,3-triazole (BTT) was synthesized by a new method. Its structure was characterized by IR and 13C NMR spectroscopy and elemental analysis (EA). The thermal stability of BTT was investigated by TG-DSC technique. The kinetic parameters including activation energy and pro-exponential factor were calculated by Kissinger equation. The combustion heat, detonation products, hygroscopicity, impact, and friction sensitivity were also measured. The formation heat, detonation pressure, and detonation velocity of BTT were calculated. BTT has high detonation pressure and detonation velocity (P=35.36 GPa, D=8.971 km s-1). BTT has potential application prospect as environmentally friendly gas generant, insensitive explosive and solid propellant.
AB - 4,5-Bis(5-tetrazolyl)-1,2,3-triazole (BTT) was synthesized by a new method. Its structure was characterized by IR and 13C NMR spectroscopy and elemental analysis (EA). The thermal stability of BTT was investigated by TG-DSC technique. The kinetic parameters including activation energy and pro-exponential factor were calculated by Kissinger equation. The combustion heat, detonation products, hygroscopicity, impact, and friction sensitivity were also measured. The formation heat, detonation pressure, and detonation velocity of BTT were calculated. BTT has high detonation pressure and detonation velocity (P=35.36 GPa, D=8.971 km s-1). BTT has potential application prospect as environmentally friendly gas generant, insensitive explosive and solid propellant.
KW - 4,5-Bis(5-tetrazolyl)-1,2,3-triazole
KW - Performance
KW - Synthesis
KW - Thermal stability
UR - http://www.scopus.com/inward/record.url?scp=84956577462&partnerID=8YFLogxK
U2 - 10.1002/prep.201500192
DO - 10.1002/prep.201500192
M3 - Article
AN - SCOPUS:84956577462
SN - 0721-3115
VL - 40
SP - 954
EP - 959
JO - Propellants, Explosives, Pyrotechnics
JF - Propellants, Explosives, Pyrotechnics
IS - 6
ER -