Abstract
Energetic 3D MOFs: A structurally unique class of three-dimensional energetic metal-organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g-1.
Original language | English |
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Pages (from-to) | 14031-14035 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 52 |
Issue number | 52 |
DOIs | |
Publication status | Published - 23 Dec 2013 |
Keywords
- energetic materials
- heats of detonation
- mesoporous materials
- metal-organic frameworks
- nitrogen-rich heterocycles